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Endohedral
fullerenes, which have a molecule, atom(s),
or metal ion(s) inside the fullerene cage,
are very difficult to be produced and purified
in a large amount by traditional methods.
In this project, we are aiming to synthesize
novel endohedral fullerenes by a molecular
surgery approach, which includes making an
orifice on the surface of empty fullerenes,
inserting a small molecule or a metal ion
through the orifice, and closing the orifice
by the use of organic synthetic methodology. |
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