[Degradation and stability] Year Started : 2022

Daisuke Aoki

The development of polymer circulation system based on carbonate linkage

Research Director
Daisuke Aoki

Associate Professor
Graduate School of Engineering
Chiba University

Collaborator
Takehiro Kamiya Associate Professor
Graduate School of Agricultural and Life Sciences
The University of Tokyo
Tatsuo Taniguchi Professor
Graduate School of Engineering
Chiba University
Masazumi Tamura Associate Professor
Graduate School of Engineering
Osaka Metropolitan University
Mizuhiko Nishida Professor
Graduate school of agricultural science
Tohoku University
Shotaro Nishitsuji Associate Professor
Graduate School of Organic Materials Science
Yamagata University
Hideto Minami Professor
Graduate School of Engineering
Kobe University
Outline

In our research, carbon dioxide is effectively used as a source of polymeric materials by forming polycarbonate where each monomer is connected by carbonate linkage. After the use of polycarbonates, chemical recycling is applied to give fertilizer.

Susumu Saito

Development of upcycling catalysts for highly oxidized chemical compounds

Research Director
Susumu Saito

Professor
Integrated Research Consortium on Chemical Sciences (IRCCS)
Nagoya University

Collaborator
Mineto Uchiyama Lecturer
Graduate School of Engineering
Nagoya University
Toshiki Sugimoto Associate Professor
Institute for Molecular Science
National Institutes of Natural Sciences
Outline

Commodity plastics barely destructible/non-biodegradable are the sources of microplastics that already plague our oceans. Carbon dioxide (CO2) produced massively every year and everywhere is also posing significant issues on the way to realizing a carbon-neutral society. Game-changing catalysts are required to chemically transform those highly oxidized or oxygenated compounds (HOCs) which are thermodynamically and kinetically highly stable. We develop novel reductive systems involving H2 and H2O as hydrogen and electron sources for tackling those extremely challenging upcycling transformations of HOCs, where molecularly well elaborated, oligomeric metal complex catalysts, semiconductor photo-catalysts, and metal complex-immobilized electrode catalysts are explored and effectively used under different energy inputs including heat, light, and electricity.

Tsuguyuki Saito

Precise control of the nano-decomposition and reassembly of plant cell walls

Research Director
Tsuguyuki Saito

Professor
Graduate School of Agricultural and Life Sciences
The University of Tokyo

Collaborator
Kayoko Kobayashi Assistant Professor
Graduate School of Agriculture
Kyoto University
Masaya Nogi Professor
SANKEN
Osaka University
Shuji Fujisawa Associate Professor
Graduate School of Agricultural and Life Sciences
The University of Tokyo
Outline

Cellulose nanofibers (CNFs) with excellent mechanical and thermal properties are produced via nano-decomposition of wood cell wall cellulose. In this project, we produce defect-free CNFs through nano-decomposition control of cell walls and further establish a technical platform for tailoring material properties of hierarchical CNF structures/composites through controls of CNF configuration and inter-CNF bonding.

Yoshinori Takashima

Precise Material Science with Dual Degradation Control Techniques

Research Director
Yoshinori Takashima

Professor
Graduate School of Science
Osaka University

Collaborator
Yasutomo Uetsuji Professor
Faculty of Engineering
Osaka Institute of Technology
Hiroshi Uyama Professor
Graduate School of Engineering
Osaka University
Takashi Konishi Assistant Professor
Graduate School of Human and Environmental Studies
Kyoto University
Outline

The research project aims to establish “dual degradation control techniques” combining “dynamic degradation control of reversible bonds” and “degradation control of covalent bonds”. Based on the “dual degradation control techniques,” the project will establish a scientific theory for the controls of degradation, deterioration, and stabilization. In particular, the project will achieve on-demand degradation through chemical and enzymatic degradation. We will develop the strategies for triple-cross network materials using chemicals from the degradation process and upcycling with the help of composite technology utilizing the on-demand degradation techniques. Finally, the project will achieve “self-healing and stabilization based on reversible bonding” and “degradation control regarding materials recyclingā€¯.

Takuya Matsumoto

Design of multi-hierarchical and self-assembled composite materials

Research Director
Takuya Matsumoto

Professor
Graduate School of Medicine, Dentistry and Pharmaceutical Sciences
Okayama University

Collaborator
Taiji Adachi Professor
Institute for Frontier Life and Medical Sciences
Kyoto University
Takaharu Okajima Professor
Graduate School of Information Science and Technology
Hokkaido University
Aira Matsugaki Associate Professor
Graduate School of Engineering
Osaka University
Outline

In this research, we regard “bone”, which functions are precisely controlled by decomposition and stabilization, as a structural and functional composite material, and analyze decomposition and stabilization in bone formation and metabolic processes in a cross-hierarchical manner. We aim to learn from creations of the nature and design artificial inorganic/organic composite materials that surpass it. The execution of this research will contribute to the improvement of sustainability and the bioecosystem, such as the development of high-strength and toughness medical materials, high-performance detoxification materials, and environmental purification materials that are superior to those of biological hard tissue.

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