相互侵入型相分離ポリマーの合成と3Dナノ構造有機薄膜太陽電池への応用
東原 知哉
論文
- Jin Wang, Mitsuru Ueda and Tomoya Higashihara,
"Synthesis and morphology of all-conjugated donor-acceptor block copolymers based on poly(3-hexylthiophene) and poly(naphthalene diimide)",
J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1139-1148.
- Jin Wang, Tomoya Higashihara, and Mitsuru Ueda,
"Synthesis of All-conjugated Donor-acceptor Block Copolymers and Their Application in All-polymer Solar Cells",
Polym. Chem. 2013, 4, 5518-5526.
- Jin Wang, Tomoya Higashihara, Mitsuru Ueda,
"Synthesis of All-Conjugated Donor-Acceptor-Donor ABA-Type Triblock ",
ACS Macro Lett.2, 506-510 (2013).
- Jin Wang, Chien Lu, Tetsunari Mizobe, Mitsuru Ueda, Wen-Chang Chen, and Tomoya Higashihara,
"Synthesis and Characterization of All-Conjugated Graft Copolymers Comprised of n-Type or p-Type Backbones and Poly(3-hexylthiophene) Side Chains",
Macromolecules, 46, 1783-1793 (2013).
- Tomoya Higashihara, Mitsuru Ueda,
"Precision Synthesis of Tailor-made Polythiophene-based Materials and Their Application to Organic Solar Cells",
Macromol. Res., 21, 257-271 (2013).
- Jin Wang, Chien Lu, Tetsunari Mizobe, Mitsuru Ueda, Wen-Chang Chen, and Tomoya Higashihara,
"Synthesis and Characterization of All-Conjugated Graft Copolymers Comprised of n-Type or p-Type Backbones and Poly(3-hexylthiophene) Side Chains",
Macromolecules, 46, 1783-1793 (2013).
- Hiroyuki Fujita, Tsuyoshi Michinobu, Masatoshi Tokita, Mitsuru Ueda, Tomoya Higashihara,
"Synthesis and Postfunctionalization of Rod–Coil Diblock and Coil–Rod–Coil Triblock Copolymers Composed of Poly(3-hexylthiophene) and Poly(4-(4′-N,N-dihexylaminophenylethynyl)styrene) Segments",
Macromolecules, 45, 9643-9656 (2012).
- Tomoya Higashihara, Hung-Chin Wu, Tetsunari Mizobe, Chien Lu, Mitsuru Ueda, Wen-Chang Chen,
"Synthesis of Thiophene-Based π-Conjugated Polymers Containing Oxadiazole or Thiadiazole Moieties and Their Application to Organic Photovoltaics",
Macromolecules, 45, 9046-9055 (2012).
- Takahashi, Ayumi; Lin, Chih-Jung; Ohshimizu, Kaoru; Higashihara, Tomoya,
"Synthesis and Caracterization of Novel Polythiophenes with Graphene-like Structures via Intramolecular Oxidative Coupling",
Polym. Chem. 3, 479-485 (2012).
- Higashihara, Tomoya; Goto, Eisuke; and Mitsuru Ueda,
"Purification-free and Protection-free Synthesis of Regioregular Poly(3-hexylthiophene) and Poly(3-(6-hydroxyhexyl)thiophene) Using a Zincate Complex of tBu4ZnLi2 ",
ACS Macro Lett. 1, 167-170 (2012).
- Y. C. Lai, T. Higashihara, J. C. Hsu, M. Ueda, W. C. Chang,
"Enhancement of power conversion efficiency and long-term stability of P3HT/PCBM solar cells using C60 derivatives with thiophene units as surfactants",
Solar. Eng. Mater. Solar Cells, in press.
- T. Higashihara, K. Oshimizu, Y. Ryo, T. Sakurai, A. Takahashi, S. Nojima, M. Ree, M. Ueda,
"Synthesis and characterization of block copolythiophene with hexyl and triethylene glycol side chains",
Polymer, 52, 3687-3695 , 2011.
- Oshimizu, Kaoru; Takahashi, Ayumi; Higashihara, Tomoya; Ueda, Mitsuru,
"Synthesis of Poly(m-phenylene) and Poly(m-phenylene)-block-Poly(3-hexylthiophene) with Low Polydispersity",
J. Polym. Sci., Part A, Polym. Chem. 49, 2709-2714 (2011).
- Y. C. Lai, K. Oshimizu, A. Takahashi, J. C. Hsu, T. Higashihara, M. Ueda, W. C. Chang,
"Synthesis of all-conjugated poly(3-hexylthiophene)-block- poly(3-(4’-(3’’,7’’-dimethyloctoxy)-3’-pyridinyl)thiophene) and its blend for photovoltaic applications",
J. Polym. Sci., Part A, Polym. Chem. 49, 2577-2587, 2011.
口頭発表・ポスター発表
- Tomoya Higashihara,
"Synthesis and Morphology of Well-defined Block Copolymers Containing ",
University of Bordeaux, LCPO: Invited Lecture, 2014/3/26.
- Tomoya Higashihara and Eisuke Goto,
"Controlled synthesis of low-polydisperse regioregular poly(3-hexylthiophene) and related materials by zincate-complex metathesis polymerization",
Polymer Journal. 2014, ASAP, doi:10.1038/pj.2014.14, 2014/3/26.
- Tomoya Higashihara,
"Precision Synthesis of Tailor-made Polythiophene-based Materials and Their Application to Organic Solar Cells",
The 3rd International Symposium of Green Map Institute and Life 3D-Printing Innovation Center at Yamagata University (Yonezawa, Japan), 2014/1/24.
- 東原知哉、
「ポリチオフェンの精密合成と有機薄膜太陽電池材料への応用」、
第49回茨城地区活動講演会 (高分子学会関東支部、住友化学(株)), 2013/11/27.
- Tomoya Higashihara,
"Precision Synthesis of Regioregular Poly(3-hexylthiophene) Using Zincate Complex",
The 13th Pacific Polymer Conference (PPC2013) (Kaohsiung, Taiwan), 2013/11/17.
- Seijiro Fukuta, Tetsunari Mizobe, Mitsuru Ueda, Hideharu Mori, and Tomoya Higashihara,
"Synthesis of New Thiadiazole-containing Polythiophene Derivatives",
The 13th Pacific Polymer Conference (PPC2013) (Kaohsiung, Taiwan), 2013/11/17.
- Tomoya Higashihara,
"Precision Synthesis of Regioregular Poly(3-hexylthiophene) Using Zincate Complex",
10th IUPAC International Conference on Advanced Polymers via Maclomolecular, 2013/8/18.
- Eisuke Goto, Mitsuru Ueda, Hideharu Mori, and Tomoya Higashihara,
"Controlled Synthesis of Poly(3-hexylthiophene) Using Zincate Complex",
Yamagata University - Hanyang University - Korea University Student Workshop, 2013/8/5.
- 青柳 晃太朗、荘司 優、大坪 才華、松本 英俊、上田 充、東原 知哉、
「ペリレンジイミド骨格を有する新規アクセプター材料の開発及びフラーレンフリー有機薄膜太陽電池への応用」、
第62回高分子年次大会 (国立京都国際会館)、2013/5/29.
- 後藤 栄祐、東原 知哉、上田 充、
「亜鉛アート錯体を用いたポリ(3-ヘキシルチオフェン)の精密合成」、
第62回高分子年次大会 (国立京都国際会館)、2013/5/29.
- 東原 知哉,
"Precision Synthesis of Tailor-made Polythiophene-based Materials and ThierApplication to Organic Solar Cells",
第93春季年会Asian International Symposium-Polymer-(立命館大学、滋賀), 2013/3/24.
- 東原 知哉、
"Synthesis of Block Copolymers and Their Application to Organic Photovoltaics",
4th International Symposium for Young Organic Chemists (ISYOC) (NIMS, Tsukuba), 2013/3/8.
- 東原 知哉、
「含ポリチオフェン鎖共重合体の合成と有機薄膜太陽電池への応用」、
グループ研究セミナー「先端光科学技術と光機能性材料開発の最前線」 (横浜国大)、2012/12/21
- Jin Wang, Tomoya Higashihara, and Mitsuru Ueda,
"All-conjugated Graft Copolymers with P3HT Brushes via Grafting-From Process",
The 9th SPSJ International Polymer Conference (IPC 2012), 2012/12/14.
- Tomoya Higashihara, Mitsuru Ueda, and Moonhor Ree,
"Synthesis of Block Copolymers with Poly(3-hexylthiophene) Segments and Their Application to Organic Photovoltaics",
The 9th SPSJ International Polymer Conference (IPC 2012), 2012/12/14.
- 東原 知哉、
「ポリチオフェン鎖を含むポリマー群の精密合成と有機薄膜太陽電池への応用」、
講演会 (山形大学)、2012/11/5
- 東原 知哉、Ryo Yecheol、Ree Moonhor、上田 充、
「半導体ブロック共重合体の合成と有機薄膜太陽電池への応用」、
第61回高分子討論会 (名古屋工業大学)、2012/9/19
- Higashihara Tomoya,
"Enhancement of Power Conversion Efficiency and Long-term Stability of P3HT/PCBM Solar Cells Using C60Derivatives with Thiophene Units as Surfactants",
JSTさきがけ研究領域合同国際シンポジウム「持続する社会を先導する光科学:環境・エネルギー・機能材料」, 2012/3/27.
- 東原知哉・上田充、
「東工大、製造コスト1/10」、
日経産業新聞(11面、先端技術)、2012/1/19
- Higashihara, Tomoya; Lai, Jung-Hsun; Chen, Wen-Chang; Ueda, Mitsuru,
"ENHANCEMENT OF PCE AND LONG-TERM STABILITY OF P3HT:PCBM OPV CELLS USING BLOCK COPOLYTHIOPHENES",
21st International Photovoltaic Science and Engineering Conference (PVSEC-21), 2011/12/1.
- 東原知哉, Y. C Lai, W. C. Chen, 上田充、
「新規ポリチオフェンブロック共重合体の合成と有機薄膜太陽電池への応用」
第20回ポリマー材料フォーラム(高分子学会)、2011/11/25.
- 東原知哉, Y. C Lai, W. C. Chen, 上田充、
「ポリ(3-ヘキシルチオフェン)鎖を有する新規ブロック共重合体の合成と有機薄膜太陽電池への応用」
第60回高分子討論会, S11 有機エレクトロニクスの材料技術とプロセス技術 (岡山大学)、2011/9/30.
- T. Higashihara, Y. C. Lai, J. H. Tsai, W. C. Chang, M. Ueda,
"Enhancement of P3HT/PCBM photovoltaic efficiency and stability based on surfactant approach",
IUMRS International Conference in Asia, 2011/9/22
- T. Higashihara,
"Synthesis of regioregular poly(3-hexylthiophene) with low polydispersity using a zincate complex,tBu4ZnLi2:Toward a purification-free system",
2011 Taiwan-Japan Bilateral Polymer Symposium (Hsinchu, Taiwan), 2011/9/14-17.
- T. Higashihara, M. Ueda,
"Controlled synthesis of regioregular poly(3-Hexylthiophene) with low polydispersity using zincate complex: Toward a purification-free system",
IP'11 Program, International Symposium on Ionic Polymerization
IUPAC (International Union of Pure & Applied Chemistry)、2011/7/10-15.
- Higashihara, Tomoya; Ueda, Mitsuru,
"Synthesis of Regioregular Poly(3-hexylthiophene) with Low Polydispersity Using Zincate Complex: ",
European Polymer Congress EPF 2011, Granada, Spain, 2011/6/26-7/1.
- 東原知哉・上田充、
「亜鉛アート錯体を用いたポリ(3-ヘキシルチオフェン)の一次構造制御」、
高分子年次大会、大阪国際会議場、2011/5/25-27
- 東原知哉・上田充、
「亜鉛アート錯体を用いたポリ(3-ヘキシルチオフェン)の一次構造制御」、
JST新技術説明会、2011/3/25
出版物
その他
プレス発表
受賞
- 東原知哉、
高分子学会研究奨励賞、
「精密重合法に基づいた新規ブロック共重合体の合成と有機薄膜太陽電池への応用」、
(2012年度)