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1期生 2期生 3期生
Wilfred van der Wiel 岩井 伸一郎 大岩 顕 尾上 順 近藤 高志 須田 淳 田中 健太郎 町田 友樹
松田 一成 山本 雅哉 湯浅 新治
研究者紹介
 
新しい多面体炭素ナノ物質の創製と機能発現
尾上 順 (おのえ じゅん)
(東京工業大学原子炉工学研究所 助教授)
  URL: http://www.nr.titech.ac.jp/~jonoe/

生年 1961年
出身地 大阪府
学歴
 
1985年 大阪大学理学部化学科卒業
1987年 大阪大学大学院理学研究科無機及び物理化学専攻修士課程修了
1997年 理学博士(京都大学)

職歴
 
1987年 松下電器産業(株) 半導体研究センター 社員
1990年 理化学研究所 研究員
1998年 東京農工大学非常勤講師、東北大学金属材料研究所共同研究員
1999年 理化学研究所 先任研究員
2002年  東京工業大学 助教授(原子炉工学研究所、理工学研究科原子核工学専攻)
   理化学研究所 共同研究員
 物質材料研究機構ナノマテリアル研究所客員研究員

研究歴
 
1985〜1987年
(川合知二助教授:大阪大学産業科学研究所)
(1) 半導体微粒子光触媒を用いた生体関連物質の生成とそのメカニズム
1987〜1989年
(2) 16MDRAM用配線材料の開発研究
1990〜2002年
(3) 分子法レーザーウラン濃縮プロセスにおける238UF6-235UF5同位体交換反応に関する研究
(4) 重原子を含む系の電子構造および化学結合における相対論効果に関する理論的研究(第28回日本原子力学会奨励賞、第2回DV-Xα研究協会奨励賞)
(5) UF分子クラスターの幾何構造と振動モードに関する研究
(6) フラーレン固体の相転移の振動分光学的研究
(7) 金属クラスターの幾何構造に関する理論的研究
(8) フラーレンポリマーの構造と電子物性に関する研究
2002年〜現在
(9) 新しい多面体ナノカーボンの創製と機能発現
(10) ナノ構造ユニットを用いる機能性薄膜の創成
(11) 相対論密度汎関数法を用いたf電子系錯体・固体に関する研究
 
発表論文リスト >>>さきがけ研究
 
[1] J. Onoe, T. Kawai, and S. Kawai: Chem. Lett., 1667-1670 (1985).
"Peptide Formation from Amino Acid with Particulate Semiconductor Photocatalysts"

[2] J. Onoe and T. Kawai: J. Chem. Soc., Chem. Commun., 1480-1481 (1987).
Photochemical Formation of Glycine and Methylamine from Glycolic Acid and Ammonia in the Presence of Particulate Cadmiun Sulphide"

[3] T. Kawai and J. Onoe: J. Electrochem. Soc. 134, 461-467 (1987).
"Photochemical Amino Acid, Peptide, and Nucleic Acid Base Formation with Particulate Semiconductors"

[4] J. Onoe and T. Kawai: Prog. 9th Int. Cong. Catalyst Vol.5, 1530-1537 (1988).
"Photochemical Peptide Formation from Amino Acid with Particulate Semiconductors"

[5] J. Onoe and T. Kawai: J. Chem. Soc., Chem. Commun., 681-683 (1988).
"Photochemcial Nucleic Acid Base Formation with Particulate Semiconductors under Irradiation"

[6] J. Onoe, H. Yamamoto, and H. Fujita: Mat. Res. Soc. Symp. (Tungsten and Other Advanced Metals for VLSI/ULSI Applications V), 325-331 (1989).
"Electromigration Characteristics in Small Via Holes Using Tungsten Encapsulated Al-Si Interconnects"

[7] J. Onoe, Y. Kuga, S. Isomura,and K. Takeuchi: J. Nucl. Sci. Technol. 28, 777-779 (1991).
"Isotope Exchange Reaction between U-235 Enriched Uranium Pentafluoride Particles and Natural Uranium Hexafluoride Gas"

[8] J. Onoe, Y. Kuga, and K. Takeuchi: Radioisotopes 41, 135-139 (1992).
"A New Calculation Method for Simulation of the Growing Particles-Gas Reaction System"

[9] J. Onoe, K. Takuechi, H. Nakamatsu, T. Mukoyama, R. Sekine, and H. Adachi: J. Electron Spectrosc. Relat. Phenom. 60, 29-36 (1992).
"DV-DS calculation on XPS for the valence levels of UF"

[10] J. Onoe, K. Takeuchi, H. Nakamatsu, T. Mukoyama, R. Sekine and H. Adachi: Chem. Phys. Lett. 196, 636-640 (1992).
"Theoretical Study of UV Excited States of UF using the Discrete-Variational Dirac-Slater Calculation Model"

[11] J. Onoe, N. Uehara, Y. Iimura, T. Oyama, O. Suto, Y. Shimazaki,and K. Takeuchi: J. Nucl. Mater. 207, 205-211 (1993).
"Characterization of UF5 ultrafine particles using TEM, XPS and XRD"

[12] J. Onoe, K. Takeuchi, H. Nakamatsu, T. Mukoyama, R. Sekine, I.-l. Kim, and H. Adachi: J. Chem. Phys. 99, 6810-6817 (1993).
"Relativistic effects on the electronic structure and chemical bonding of UF"

[13] J. Onoe, H. Nakamatsu, T. Mukoyama, R. Sekine, H. Adachi, and K. Takeuchi: Chem. Phys. Lett. 217, 61-64 (1994).
"Atomic-number dependence of the relativistic effects on chemical bonding using the non-relativistic and relativistic discrete-variational Xa methods"

[14] J. Onoe, T. Oyama, and K. Takeuchi: Rev. Laser Eng. 22, 213-215 (1994).
"Formation of C from a BCl and CH gas mixture irradiated with a TEA CO laser "

[15] J. Onoe, K. Takeuchi, H. Nakamatsu, T. Mukoyama, R. Sekine, and H. Adachi: J. Electron Spectrosc. Relat. Phenom. 70, 89-93 (1994).
"Theoretical study of the valence photoelectron spectrum of UF"

[16] J. Onoe, K. Takeuchi, H. Nakamatsu, T. Mukoyama, and H. Adachi: J. Phys. Soc. Jpn. 63, 3992-3995 (1994).
"Note on the contribution of relativity to Cu bonding"

[17] J. Onoe and K. Takeuchi: J. Phys. Chem. 99, 16786-16791 (1995).
"In situ high-resolution FT-IR study of the orientational phase transition in C film"

[18] J. Onoe, H. Nakamatsu, T. Mukoyama, R. Sekine, H. Adachi, and K. Takeuchi: J. Phys. Soc. Jpn. 65, 2459-2462 (1996).
"Relativistic change in bond overlap population for the study of relativistic effects on bond length of diatomic molecules"

[19] Y. Okada, H. Okamura, J. Onoe, A. Suda, H. Tashiro, K. Takeuchi: Appl. Phys. B 63, 57-61 (1996).
"Vibrational predissociation of UF60 clusters in supersonic Laval nozzle flow"

[20] M. Hirata, H. Monjushiro, R. Sekine, J. Onoe, H. Nakamatsu, T. Mukoyama, H. Adachi and K. Takeuchi: J. Electron Spectrosc. Relat. Phenom. 83, 59-64 (1997).
"Valence electronic structure of uranyl nitrate UO(NO)・2HO"

[21] J. Onoe and K. Takeuchi: Phys. Rev. B 54, 6167-6171 (1996)
"In situ high-resolution infrared spectroscopy of a photopolymerized C film"

[22] J. Onoe, H. Nakamatsu, T. Mukoyama, R. Sekine, H. Adachi, and K. Takeuchi: Inorg. Chem. 36, 1934-1938 (1997).
"Structure and Bond Nature of the UF5 Monomer"

[23] Y. Kuga, J. Onoe, S. Isomura, and T. Takeuchi: J. Nucl. Sci. Technol. 33, 889-891 (1996). "Effect of UF6-UF6 Gas Mixing on the Kinetic Rate of the Isotope Exchange Reaction between U-Enriched UF Nanoparticles and Natural UF Gas"
[24] T.A. Beu, J. Onoe, and K. Takeuchi: J. Chem. Phys. 106, 5910-5919 (1997)
"Calculations of Structure and IR-spectrum for small UF clusters"

[25] J. Onoe, A. Nakao, and K. Takeuchi: Phys. Rev. B 55, 10051-10056 (1997).
"XPS study of a photopolymerized C film"

[26] T.A. Beu, J. Onoe, and K. Takeuchi: J. Mol. Struct. 410-411, 295-298 (1997).
"Structure and frequency shift calculations for small UF clusters"

[27] J. Onoe: J. Phys. Soc. Jpn. 66, 2328-2336 (1997).
"Relativistic Effects on Covalent Bonding: Role of Individual Valence Atomic Orbitals"

[28] J. Onoe and K. Takeuchi: Phys. Rev. Lett. 79, 2987-2989 (1997).
"How many [2+2] four-membered rings are formed on a C molecule when photopolymerization is saturated?"

[29] K. Takeuchi, Y. Kuga, Y. Okada, and J. Onoe: J. Nucl. Sci. Technol. 34, 1110-1111 (1997).
"A critical comment on the previous models for F-atom transfer reaction from UF to UF"

[30] R. Sekine, H. Nakamatsu, T. Mukoyama, J. Onoe, M. Hirata, M. Kurihara, and H. Adachi: Adv. Quantum Chem. 29, 123-136 (1997).
"Electronic Structures of Metal Carbides TiC and UC:Similarity and Dissimilarity"

[31] M. Hirata, R. Sekine, J. Onoe, H. Nakamatsu, T. Mukoyama, K. Takeuchi, and S. Tachimori: J. Alloy and Compounds 271-273, 128-132 (1998).
"The electronic structures of actinyl nitrate-triethyl phosphate complexes using the DV-DS method"

[32] A. Nakao, J. Onoe, and K. Takeuchi: Surf. Sci. Spectra 5, 313-317 (1998).
"Photopolymerized C film by XPS"

[33] T. Hara, J. Onoe, and K. Takeuchi: J. Phys. Chem. B101, 9532-9536 (1997).
"In situ high-resolution FT-IR study of the grass transition in a C film"

[34] K. Esfarjani, Y. Hashi, J. Onoe, K. Takeuchi, and Y. Kawazoe: Phys. Rev. B 57, 223-229 (1998).
"Vibrational modes and IR analysis of neutral photopolymerized C dimers"

[35] S. Osawa, J. Onoe, and K. Takeuchi: Fullerene Sci. Technol. 6, 301-308 (1998).
"Coalescence of [60] Fullerene Molecules in Toluene under Ultrahigh Pressure"

[36] J. Onoe, K. Ohno, Y. Kawazoe, and K. Takeuchi: J. Vac. Sci. Technol. A 16, 385-388 (1998).
"X-ray photoelectron spectroscopy of air-exposed C films: Origin of the O 1s core peak"

[37] J. Onoe and K. Takeuchi: J. Mass Spectromet. 33, 387-391 (1998). "Photo-induced coalescence of C molecules in a pottasium-doped C film: mass spectral evidence"
[38] T.A. Beu, J. Onoe, and K. Takeuchi: J. Chem. Phys. 109, 8295-8303 (1998).
"Homogeneous and mixed UF clusters with Ar: Calculations of structures and IR spectra"

[39] J. Onoe, Y. Kuga, and K. Takeuchi: J. Nucl. Sci. Technol. 36, 108-109 (1999).
"A note on the inhibition of the isotope exchange reaction between U-enriched UF nanoparticles and natural UF gas"

[40] M. Kurihara, M. Hirata, R. Sekine, J. Onoe, H. Nakamatsu, T. Mukoyama, and H. Adachi: J. Alloys and Compounds 283, 128-132 (1999).
"Discrete-Variational Dirac-Slater Calculation on Valence Band XPS for UC"

[41] J. Onoe, Y. Hashi, K. Esfarjani, Y. Kawazoe, and K. Takeuchi: Eur. Phys. J. D 9, 363-367 (1999).
"FT-IR and FT-MS studies of a photoirradiated KxC film"

[42] T. Nakayama, J. Onoe, K. Takeuchi, and M. Aono: Phys. Rev. B 59, 12627-12631 (1999). "Weakly bound C monolayer on Si(111)√3x√3R30°-Ag substrate surface"
[43] H. Tanaka, S. Osawa, J. Onoe, and K. Takeuchi: J. Phys. Chem. B 103, 5939-5942 (1999).
"Formation process of Si-coated C"

[44] Y. Kuga, K. Ando, J. Onoe, and K. Takeuchi: J. Phys. Chem. B 103, 7452-7455 (1999).
"Activation energy for the isotope exchange reaction between UF nanoparticles and UF gas"

[45] J. Onoe, Y. Hashi, K. Esfarjani, T. Hara, Y. Kawazoe, and K. Takeuchi: Chem. Phys. Lett. 315, 19-24 (1999).
"In situ infrared spectroscopy of a photoirradiated potassium-doped C film"

[46] T. Nakayama, J. Onoe, K. Nakatsuji, J. Nakamura, K. Takeuchi, and M. Aono: Surf. Rev. Lett. 6, 1073-1078 (1999).
"Photo-induced products in a C monolayer on Si(111)√3x√3R30°-Ag : An STM study"

[47] M. Hirata, T. Bastug, S. Tachimori, R. Sekine, J. Onoe, and H. Nakamatsu: Adv. Quantum Chem. 37, 325-334 (2000).
"Relativistic Density-Functional calculation for potential energy curves of uranyl nitrate hydrate"

[48] T. Hara, J. Onoe, H. Tanaka, and K. Takeuchi: Mol. Cryst. Liq. Cryst. 340, 695-700 (2000).
"In situ FT-IR study of an electron-beam induced reaction of C film"

[49] J. Onoe, T. Nakayama, A. Nakao, Y. Hashi, K. Esfarjani, Y. Kawazoe, M. Aono, and K. Takeuchi: Mol. Cryst. Liq. Cryst. 340, 689-694 (2000).
"In situ FTIR, XPS, and STM studies of the nano-structure of a photopolymerized C film"

[50] H. Tanaka, J. Onoe, T. Hara, A. Nakao, and K. Takeuchi: Mol. Cryst. Liq. Cryst. 340, 701-705 (2000).
"Investigation of the interaction between C and Si atom"

[51] J. Onoe: Adv. Quantum. Chem. 37, 311-324 (2000).
"Atomic-number dependence of relativistic effects on chemical bonding"

[52] T. A. Beu, J. Onoe, and K. Takeuchi: Eur. Phys. J. D 10, 391-398 (2000).
"Simulation of Raman spectra of C and C by non-othogonal tight-binding molecular dynamics".

[53] T. Hara, J. Onoe, and K. Takeuchi: Jpn. J. Appl. Phys. 39, 1872-1876 (2000).
"In situ Fourier-Transform infrared study of electron-irradiation-induced reaction in a C film"

[54] K. Tanaka, R. Sekine, J. Onoe, and H. Nakamatsu: Adv. Quantum Chem. 37, 375-384 (2000).
"Nature in chemical bonding for sulfur fluorides"

[55] R. Sekine, K. Tanaka, J. Onoe, K. Takeuchi, and H. Nakamatsu: Adv. Quantum Chem. 37, 237-254 (2000).
"Analysis of chemical bond for metal clusters: I. Alkali metal and alkaline earth metals"

[56] J. Onoe, K. Ohno, Y. Kawazoe and K. Takeuchi: Trans. Mater. Res. Soc. Jpn. 25, 1011-1014 (2000).
"XPS and ab initio MD studies of an air-exposed C film"

[57] T. Hara, J. Onoe, and K. Takeuchi: Trans. Mater. Res. Soc. Jpn. 25, 1041-1044 (2000).
"Density-functional calculations of the normal vibrations for the triplet excited state of C"

[58] H. Tanaka, J. Onoe, T. Hara, and K. Takeuchi: Trans. Mater. Res. Soc. Jpn. 25, 1045-1047 (2000).
"XPS study of SixC thin films"

[59] R. Kondo, R. Sekine, J. Onoe, and H. Nakamatsu: Trans. Mater. Res. Soc. Jpn. 25, 967-970 (2000).
"Geometric and electronic structures of Fe- (n=2-8) clusters"

[60] R. Kondo, R. Sekine, J. Onoe, and H. Nakamatsu: J. Surf. Sci. Soc. Jpn. 21, 462-467 (2000).
"Geometric and electronic structures of V and Cr clusters"

[61] M. Hirata, S. Tachimori, R. Sekine, J. Onoe, and H. Nakamatsu: Adv. Quantum Chem. 37, 335-352 (2000).
"Electronic structures and chemical bonding of actinyl nitrates dihydrates"

[62] M. Kurihara, M. Hirata, R. Sekine, J. Onoe, H. Nakamatsu: J. Nucl. Mater. 281, 140-145 (2000).
"Discrete-Variational Dirac-Slater Calculation on Valence Band XPS for α-Uranium Metal"

[63] T. Hara, J. Onoe, and K. Takeuchi: Phys. Rev. B 63, 115412 (2001).
"Normal vibrational analysis of the triplet excited state of C"

[64] J. Onoe, T. Hara, and K. Takeuchi: Synthetic Metals 121, 1141-1142 (2001).
"Kinetic study of an electron-beam irradiated C film using in situ infrared spectroscopy"

[65] T. Hara, J. Onoe, and K. Takeuchi: Trans. Mater. Res. Soc. Jpn. 26, 1171-1174 (2001).
"Enhanced field-emission characteristics of an electron-beam irradiated C film

[66] R. Sekine, A. Sagawa, T. Urago, R. Kondo, K. Tanaka, J. Onoe, and H. Nakamatsu: Trans. Mater. Res. Soc. Jpn. 26, 1109-1112 (2001).
"Density-functional study of Cu and Zn clusters: Comparison with Na and Mg clusters"

[67] H. Tanaka, J. Onoe, and K. Takeuchi: Trans. Mater. Res. Soc. Jpn. 26, 1175-1178 (2001).
"In situ XPS study of Si-deposited C thin films"

[68] T.A. Beu, J. Onoe, and K. Takeuchi: Eur. Phys. J. D 17, 205-212 (2001).
"Structural and vibrational properties of C and its oligomers (C)M= by tight-binding molecular dynamics"

[69] T. Hara, J. Onoe, and K. Takeuchi: J. Appl. Phys., in press. "Field emission from an electron-beam irradiated C film"
[70] H. Tanaka, J. Onoe, and K. Takeuchi: Surf. Sci., under revision for acceptance. "In situ X-ray photoelectron spectroscopic study of Si-deposited C films"
[71] J. Onoe, T. Nakayama, T. Hara: Appl. Phys. Lett., in press.
"The structural and electrical properties of an electron-beam irradiated C film"

[72] T. Hara and J. Onoe: Eur. Phys. J. D, in press.
"Vibrational analysis of peanut-shaped C fullerenes".

[73] J. Onoe, T. Hara, and T. Nakayama: Phys. Rev. B, submitted.
"The electron transport property of a two-dimensionally hexagonal C photopolymer".

[74] R. Sekine, R. Kondo, T. Yamamoto, and J. Onoe: submitted.
"Geometric and electronic structures for Tc and Mn clusters by density functional calculations"

 
 
【解説】
1) 尾上 順,川合知二:化学 42, 718 (1987).
"光化学から生命の起源を考える"
2) 尾上 順,川合知二:化学工業 39, 201 (1988).
"半導体微粒子光触媒を用いたアミノ酸生成"
3) 尾上 順,川合真紀,川合知二:表面 26, 825 (1988).
"レーザー誘起表面反応とプロセスへの応用"
4) 尾上 順,武内一夫:化学工学 54, 654 (1990).
"半導体微粒子の表面光化学"
5) 尾上 順,武内一夫:粉体と工業 22, 1 (1990).
"半導体微粒子の光・化学エネルギー変換機能とその応用"
6) 尾上 順:化学工学 55, 552 (1991).
"原子1個1個を制御する究極"技(わざ)"〜走査トンネル電子顕微鏡によるアトムマニュピレーション〜"
7) 尾上 順,武内一夫:化学と工業 46, 100 (1993)
"ダイヤモンドの熱伝導性に対する異常アイソトープ効果"
8) 尾上 順:化学と教育 44 (5), 314 (1996).
"フラーレン、その後"
9) Jun Onoe and Kazuo Takeuchi: RIKEN Review 15, 87 (1997).
"Spectroscopic study of a photopolymerized C60 film using FT-IR and XPS"
10) Titus A. Beu, Jun Onoe, and Kazuo Takeuchi: RIKEN Review 15, 89 (1997).
"Intermolecular potential, structure and IR-spectrum calculations for small UF clusters"
11) Jun Onoe and Kazuo Takeuchi: RIKEN Review 17, 49 (1998).
"XPS study of the saturation number of [2+2] rings formed on a C molecule in a photopolymerized C film"
12) Shuichi Osawa, Jun Onoe, and Kazuo Takeuchi: RIKEN Review 17, 51 (1998).
"Coalesced C in Toluene under High Pressure"
13) 尾上 順、武内一夫:化学工業 50 (1), 7-21 (1999).
"フラーレン光重合ポリマーのナノ構造"
14) 尾上 順、中山知信、武内一夫、青野正和:季刊フラーレン 7, 129-146 (1999).
"フラーレン光重合ポリマー:現状と展望"
15) 尾上 順:JAERI-Review (99-008), 11-13 (1999).
"ウラン化合物の化学結合"
16) 尾上 順:季刊フラーレン 8, 123-135 (2000).
"研究室紹介(第30回)〜理化学研究所レーザー反応工学研究室〜"
17) J. Onoe, T. Nakayama, M. Aono, and K. Takeuchi: RIKEN Review 33, 39-40 (2001).
"In situ x-ray photoelectron spectroscopic and scanning tunneling miscroscopic studies of the structure of C photopolymers"
18) H. Tanaka, J. Onoe, T. Hara, and K. Takeuchi: RIKEN Review 33, 41-43 (2001).
"Investigation of Si-coated C"
19) 中山知信、尾上 順、武内一夫、青野正和:バウンダリー 17, 30-36 (2001).
"フラーレンポリマー形成のナノスコピック観察"
20) 尾上 順、中山知信、武内一夫、青野正和:材料科学38, 242-249 (2001).
" フラーレンポリマーの構造・性質・応用"
21) J. Onoe and T. Nakayama: Encyclopedia of Nanosci. & Nanotechnol., to be published (2002).
"A new polyhedral form of carbon materials using fullerenes" (invited paper)
   
【本】
1) 尾上 順、武内一夫(分担執筆):先端レーザーテクノロジー、日経技術図書、p.435 (1992). "その他のレーザー同位体分離〜現状と展望〜"
2) J. Onoe, T. Nakayama, A. Nakao, Y. Hashi, K. Esfarjani, K. Ohno, Y. Kawazoe, M. Aono, and K. Takeuchi: Clusters and Nanomaterials (Springer Series in Cluster Physics), Springer-Verlag, pp. 135-169 (2001).
   
【特許】
1) 田島右副、尾上 順、石井忠浩、武内一夫;"フラーレン含有高分子材料及びその製造方法"、特開平9-188726 (1997).
2) 中山知信、尾上 順、武内一夫、青野正和:"極微細構造およびその製造方法"、特願2000-265572、平成12年9月1日出願 (2000).
 
※「1期生」 = 平成13年度採用研究者 2001年〜2004年
※「2期生」 = 平成14年度採用研究者 2002年〜2005年
※「3期生」 = 平成15年度採用研究者 2003年〜2006年
 
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