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Yutaka Matsuo
松尾 豊
(まつお ゆたか)

・ERATO 中村活性炭素クラスタープロジェクト 機能素子グループ グループリーダー
・東京大学大学院理学系研究科 光電変換化学講座(社会連携講座) 特任教授

学歴
平成8年3月 大阪大学基礎工学部合成化学科卒業
平成13年3月 大阪大学大学院基礎工学研究科化学系専攻博士後期課程修了 (博士(理学),谷 一英教授,真島和志助教授)

職歴
平成10年4月 日本学術振興会特別研究員(DC1)
平成13年4月 東京大学大学院理学系研究科化学専攻 助手(中村栄一教授)
平成16年12月 科学技術振興機構 ERATO中村活性炭素クラスタープロジェクト グループリーダー
平成21年4月 東京大学大学院理学系研究科 光電変換化学講座(社会連携講座) 特任教授

受賞
・第55回 日本化学会 進歩賞(平成17年度)
・フラーレン・ナノチューブ学会 第3回 大澤賞(平成19年2月)
・Perdersen Lectureship (DuPont) (平成19年7月)
・錯体化学会研究奨励賞(平成21年9月)
・東京大学化学イノベーションGCOEレクチャーシップ賞(平成22年2月)
・文部科学大臣表彰 若手科学者賞(平成22年4月)

学会貢献・その他活動
・日本化学会 新領域研究グループ「金属と分子集合
・新学術領域研究「高次π空間の創発と機能開発」(領域代表:筑波大学 赤阪 健 先生)班友
・JST/CREST「計算科学によるグラファイト系材料の基礎物性解明とそのデバイス応用における設計指針の開発」(研究代表者:筑波大学 岡田 晋 先生)アドバイザー
・環境省委託研究「新規ナノマテリアルを用いた超フレキシブル有機太陽電池の研究」(研究代表者:表 研次 博士) アドバイザー
・日本化学会 関東支部 幹事

Publications
(1) Ligand Exchange Reactions of a 1,3-Butadiene Complex of Magnesium
Kazushi Mashima, Yutaka Matsuo, Hiroki Fukumoto, Kazuhide Tani, Hajime Yasuda, and Akira Nakamura
J. Organomet. Chem. 1997, 545/546, 549-552.
(2) Nonplanar σ2,π- and Planar σ2-Enediamide Coordinations of 1,4-Di(p-methoxyphenyl) -1,4-diaza-1,3-butadiene (= MeOC6H4-DAD) on Ta(η5-C5R5) Fragments (R = H, Me): Crystal Structures of TaCl22,π-MeOC6H4-dad)(η5-C5R5) and Ta(σ2-MeOC6H4-dad)(η5-C5Me5)(η4-1,3-butadiene)
Kazushi Mashima, Yutaka Matsuo, and Kazuhide Tani
Chem. Lett. 1997, 767-768.
(3) Oxidative Reaction of 1,5-Dithioniabicyclo[3.3.0]octane Bis(trifluoromethanesulfonate) with Diene Complexes of Zirconium and Tantalum: Synthesis of Cp2Zr(OTf)2 (thf) and Cp(η4-1,3-butadiene)Ta(OTf)2
Kazushi Mashima, Toshiyuki Oshiki, Yutaka Matsuo, and Kazuhide Tani
Chem. Lett. 1997, 793-794.
(4) Polymerization of Methyl Methacrylate Catalyzed by Tantalum-diene Complexes, Ta(η5 -C5R5)(η4-1,3-butadiene)2 (R = H and Me), in the presence of cocatalyst AlMe(OC6H2-2,6-(tBu)2-4-Me)2
Kazushi Mashima, Yutaka Matsuo, and Kazuhide Tani
Proc. Jpn. Acad., Ser. B 1998, 74, 217-220.
(5) Unique Complexation of 1,4-Diaza-1,3-butadiene Ligand on Half-metallocene Fragments of Niobium and Tantalum
Kazushi Mashima, Yutaka Matsuo, and Kazuhide Tani
Organometallics 1999, 18, 1471-1481.
(6) 1-Aza-1,3-butadiene Complexes of Tantalum: Preparation and Alkylation of TaCl25-C5Me5)(η4-1-aza-1,3-butadiene)
Kazushi Mashima, Yutaka Matsuo, Shinya Nakahara, and Kazuhide Tani
J. Organomet. Chem. 2000, 593/594, 69-76.
(7) Convenient Synthesis of Anionic Dinuclear Ruthenium(II) Complexes [NR2H2][{RuCl(diphosphine)}2 (μ-Cl)3] [diphosphine = 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl, 2,2' -bis(di(p-tolyl)phosphino)-1,1'-binaphthyl, and 1,2-bis(diphenylphosphino)benzene]: Crystal Structure of [NEt2H2][{RuCl(1,2-bis(diphenylphosphino)benzene)}2(μ-Cl)3]
Kazushi Mashima, Tomoko Nakamura, Yutaka Matsuo, and Kazuhide Tani
J. Organomet. Chem. 2000, 607, 51-56.
(8) Synthesis and Characterization of Bis(iminopyrrolyl)zirconium Complexes
Yutaka Matsuo, Kazushi Mashima, and Kazuhide Tani
Chem. Lett. 2000, 1114-1115.
[LINK]
(9) Half-metallocene Tantalum Complexes Bearing Methyl Methacrylate (MMA) and 1,4-Diaza-1,3-butadiene Ligands as MMA Polymerization Catalysts
Yutaka Matsuo, Kazushi Mashima, and Kazuhide Tani
Angew. Chem. Int. Ed. 2001, 40, 960-962.
[LINK]
(10) Selective Formation of Homoleptic and Heteroleptic 2,5-Bis(N-aryliminomethyl)pyrrolyl Yttrium Complexes and Their Performance as Initiators of ε-Caprolactone Polymerization
Yutaka Matsuo, Kazushi Mashima, and Kazuhide Tani
Organometallics 2001, 20, 3510-3518.
(11) Intramolecular Coupling Reaction of 1-Aza-1,3-butadiene Ligand and Iminoacyl Ligand Giving Amido-Imido Complexes of Tantalum
Yutaka Matsuo, Kazushi Mashima, and Kazuhide Tani
Organometallics 2002, 21, 138-143.
(12) Half-metallocene 1-Aza-1,3-butadiene Complexes of Tantalum: Auxiliary Ligands on Tantalum Controlling Coordination Modes of the 1-Aza-1,3-butadiene Ligand
Yutaka Matsuo, Kazushi Mashima, and Kazuhide Tani
Bull. Chem. Soc. Jpn. 2002, 75, 1291-1297.
(13) Cu(I)-Mediated Regioselective Tri-addition of Grignard Reagent to [70]Fullerene. Synthesis of Indenyl-type Metal Ligand Embedded into Graphitic Structure
Masaya Sawamura, Motoki Toganoh, Hitoshi Iikura, Yutaka Matsuo, Atsushi Hirai, and Eiichi Nakamura
J. Mater. Chem. 2002, 12, 2109-2115.
(14) Hybrid of Ferrocene and Fullerene
Masaya Sawamura, Yoichiro Kuninobu, Motoki Toganoh, Yutaka Matsuo, Masahiro Yamanaka, and Eiichi Nakamura
J. Am. Chem. Soc. 2002, 124, 9354-9355.
[LINK]
(15) Stacking of Conical Molecules with a Fullerene Apex into Polar Columns in Crystals and Liquid crystals
Masaya Sawamura, Kenji Kawai, Yutaka Matsuo, Kiyoshi Kanie, Takashi Kato, and Eiichi Nakamura
Nature 2002, 419, 702-705.
[LINK]
(16) Synthesis, Structure and Aromaticity of a Hoop-shaped Cyclic Benzenoid [10]Cyclophenacene
Eiichi Nakamura, Kazukuni Tahara, Yutaka Matsuo, and Masaya Sawamura
J. Am. Chem. Soc. 2003, 125, 2834-2835.
[LINK]
(17) Ruthenium (II) Complexes of Pentamethylated [60]Fullerene. Alkyl, Alkynyl, Chloro, Isocyanide, Phosphine Complexes
Yutaka Matsuo and Eiichi Nakamura
Organometallics 2003, 22, 2554-2563.
[LINK]
(18) Rhenium-templated Regioselective Polyhydrogenation of [60]Fullerene and Derivatives. Rhenium η5 -Complexes of Hydrofullerenes
Motoki Toganoh, Yutaka Matsuo, and Eiichi Nakamura
Angew. Chem. Int. Ed. 2003, 42, 3530-3532.
[LINK]
(19) Theoretical Studies on Structures and Reactivities of Finite-Length Single Wall Armchair Carbon Nanotubes
Yutaka Matsuo, Kazukuni Tahara, and Eiichi Nakamura
Org. Lett. 2003, 5, 3181-3184.
[LINK]
(20) Synthesis and Structural Characterization of 2,5-Bis(N-aryliminomethyl)pyrrolyl Complexes of Aluminum
Yutaka Matsuo, Hayato Tsurugi, Tsuneaki Yamagata, Kazuhide Tani, and Kazushi Mashima
Bull. Chem. Soc. Jpn. 2003, 76, 1965-1968.
(21) Synthesis and Catalytic Activity of Rhodium Diene Complexes Bearing Indenyl-Type Fullerene η5 -Ligand
Motoki Toganoh, Yutaka Matsuo, and Eiichi Nakamura
J. Organomet. Chem. 2003, 683, 295-300.
(22) Synthesis of Ferrocene/Hydrofullerene Hybrid and Functionalized Bucky Ferrocenes
Motoki Toganoh, Yutaka Matsuo, and Eiichi Nakamura
J. Am. Chem. Soc. 2003, 125, 13974-13975.
[LINK]
(23) Synthesis and Reactivity of Bucky Ruthenocene Ru(η5-C60Me5) (η5-C5H5)
Yutaka Matsuo, Yoichiro Kuninobu, Shingo Ito, and Eiichi Nakamura
Chem. Lett. 2004, 33, 68-69.
[LINK]
(24) Stacking of Molecules Possessing a Fullerene Apex and a Cup-shaped Cavity Connected by Silicon-Connection
Yutaka Matsuo, Ayako Muramatsu, Ryo Hamasaki, Norihiro Mizoshita, Takashi Kato, and Eiichi Nakamura
J. Am. Chem. Soc. 2004, 126, 432-433.
[LINK]
(25) Synthesis of Functionalized Fullerene by Mono-alkylation of Fullerene Cyclopentadienide
Ryo Hamasaki, Yutaka Matsuo, and Eiichi Nakamura
Chem. Lett. 2004, 33, 328-329.
[LINK]
(26) Intramolecular Benzylation of an Imino Group of Tridentate 2,5-Bis(N-aryliminomethyl)pyrrolyl Ligands Bound to Zirconium and Hafnium Gives Amido-Pyrrolyl Complexes That Catalyze Ethylene Polymerization
Hayato Tsurugi, Yutaka Matsuo, Tsuneaki Yamagata, and Kazushi Mashima
Organometallics 2004, 23, 2797-2805.
(27) Nickel, Palladium and Platinum Complexes of η5-Cyclopentadienide C60R5 Ligands. Kinetic and Thermodynamic Stabilization Effects of C60Ph5 Ligand
Yoichiro Kuninobu, Yutaka Matsuo, Motoki Toganoh, Masaya Sawamura, and Eiichi Nakamura
Organometallics 2004, 23, 3259-3266.
[LINK]
(28) Creation of Hoop- and Bowl-Shaped Benzenoid Systems by Selective Detraction of [60]Fullerene Conjugation. [10]Cyclophenacene and Fused Corannulene Derivatives
Yutaka Matsuo, Kazukuni Tahara, Masaya Sawamura, and Eiichi Nakamura
J. Am. Chem. Soc. 2004, 126, 8725-8734.
[LINK]
(29) Molecular Orientation and Electronic Structure of Epitaxial Bucky Ferrocene (Fe(C60(CH3)5H5)) Thin Films
Toshihiko Kaji, Toshihiro Shimada, Hiroaki Inoue, Yoichiro Kuninobu, Yutaka Matsuo, Eiichi Nakamura, and Koichiro Saiki
J. Phys. Chem. B 2004, 108, 9914-9918.
[LINK]
(30) Photoinduced Change in the Raman Spectrum of Buckyferrocene (Fe(C60(CH3)5)C5H5)
Toshihiro Shimada, Yoshiro Yamamoto, Toshihiko Kaji, Kenji Itaka, Hideomi Koinuma, Yoichiro Kuninobu, Yutaka Matsuo, Eiichi Nakamura, and Koichiro Saiki
Solid State Commun. 2004, 132, 197-201.
(31) Electronic Structure of Stacked C60 Shuttlecocks
Susumu Okada, Ryotaro Arita, Yutaka Matsuo, Eiichi Nakamura, Atsushi Oshiyama, and Hideo Aoki
Chem. Phys. Lett. 2004, 399, 157-161.
(32) Synthesis and Derivatization of Ir(I)- and Ir(III)-Pentamethyl[60]Fullerene Complexes
Yutaka Matsuo, Akihiko Iwashita, and Eiichi Nakamura
Organometallics 2005, 24, 89-95.
[LINK]
(33) Syntheses, Structure, and Derivatization of Potassium Complexes of Penta(organo)[60]fullerene-Monoanion, -Dianion, and -Trianion into Hepta- and Octa(organo)fullerenes
Yutaka Matsuo and Eiichi Nakamura
J. Am. Chem. Soc. 2005, 127, 8457-8466.
[LINK]
(34) Ball-and-Socket Stacking of Supercharged Geodesic Polyarenes: Bonding by Interstitial Lithium Ions
Ivan Aprahamian, David Eisenberg, Roy E. Hoffman, Tamar Sternfeld, Yutaka Matsuo, Edward A. Jackson, Eiichi Nakamura, Lawrence T. Scott, Tuvia Sheradsky, and Mordecai Rabinovitz
J. Am. Chem. Soc. 2005, 127, 9581-9587.
[LINK]
(35) X-ray Crystallographic Characterization of Potassium Pentaphenyl[60]fullerene
Yutaka Matsuo, Kazukuni Tahara, and Eiichi Nakamura
Chem. Lett. 2005, 34, 1078-1079.
[LINK]
(36) Mössbauer Spectroscopy of Bucky Ferrocenes: Lattice Dynamics and Motional Anisotropy of the Metal Atom
Rolfe H. Herber, Israel Nowik, Yutaka Matsuo, Motoki Toganoh, Yoichiro Kuninobu, and Eiichi Nakamura
Inorg. Chem. 2005, 44, 5629-5635.
[LINK]
(37) Organic and Organometallic Derivatives of Dihydrogen-Encapsulated [60]Fullerene
Yutaka Matsuo, Hiroyuki Isobe, Takatsugu Tanaka, Yasujiro Murata, Michihisa Murata, Koichi Komatsu, and Eiichi Nakamura
J. Am. Chem. Soc. 2005, 127, 17148-17149.
[LINK]
(38) Synthesis of 6,9,12,15,18-Pentamethyl-1,6,9,12,15,18-Hexahydro(C60-Ih)[5,6]Fullerene
Yutaka Matsuo, Ayako Muramatsu, Kazukuni Tahara, Madoka Koide, and Eiichi Nakamura; Checked by Peter Wipf and David L. Waller
Org. Synth. 2006, 83, 80-87.
(39) Synthesis of Trialkyl[60]fullerene C60(CH2SiMe3)3H and Its Potassium and Rhodium(I) Complexes
Yutaka Matsuo and Eiichi Nakamura
Inorg. Chim. Acta 2006, 359, 1979-1982.
(40) Convergent Synthesis of Polyfunctionalized Fullerene by Regioselective Five-fold Addition of Functionalized Organocopper Reagent to C60
Yu-Wu Zhong, Yutaka Matsuo, and Eiichi Nakamura
Org. Lett. 2006, 8, 1463-1466.
[LINK]
(41) Remote Chirality Transfer within Coordination Sphere by the Use of a Ligand Possessing a Concave Cavity
Yutaka Matsuo, Yuichi Mitani, Yu-Wu Zhong, and Eiichi Nakamura
Organometallics 2006, 25, 2826-2832.
[LINK]
(42) Preparation and Characterization of Iminopyrrolyl Hafnium Complexes as Catalyst Precursors for α-Olefin Polymerization
Hayato Tsurugi, Yutaka Matsuo, and Kazushi Mashima
J. Mol. Catal. A: Chem. 2006, 254, 131-137.
(43) Synthesis and Electrochemistry of Double-decker Buckyferrocenes
Yutaka Matsuo, Kazukuni Tahara, and Eiichi Nakamura
J. Am. Chem. Soc. 2006, 128, 7154-7155.
[LINK]
(44) Sharing Orbitals -Ultrafast Excited State Deactivations with Different Outcome in Bucky Ferrocenes and Ruthenocenes
Dirk M. Guldi, G. M. Aminur Rahman, Renata Marczak, Yutaka Matsuo, Masahiro Yamanaka, and Eiichi Nakamura
J. Am. Chem. Soc. 2006, 128, 9420-9427.
[LINK]
(45) Synthesis, Structural, Electrochemical and Stacking Properties of Conical Molecules Possessing Buckyferrocene on Apex
Yutaka Matsuo, Ayako Muramatsu, Yuko Kamikawa, Takashi Kato, and Eiichi Nakamura
J. Am. Chem. Soc. 2006, 128, 9586-9587.
[LINK]
(46) Coupling of Alkylarene and Pentamethyl[60]fullerene by Iridium-catalyzed Benzylic C-H Bond Activation
Yutaka Matsuo, Akihiko Iwashita, and Eiichi Nakamura
Chem. Lett. 2006, 35, 858-859.
[LINK]
(47) Chiral Ruthenium Allenylidene Complexes Bearing a Fullerene Cyclopentadienyl Ligand: Synthesis, Characterization, and Remote Chirality Transfer
Yu-Wu Zhong, Yutaka Matsuo, and Eiichi Nakamura
Chem. Asian J. 2007, 2, 358-366.
[LINK]
(48) Regioselective Octa- and Deca-additions of Pyridine-modified Organocopper Reagent to [60]Fullerene
Yutaka Matsuo, Kazukuni Tahara, Kouhei Morita, Keiko Matsuo, and Eiichi Nakamura
Angew. Chem. Int. Ed. 2007, 46, 2844-2847.
[LINK]
(49) Lamellar Assembly of Conical Molecules Possessing a Fullerene Apex in Crystals and Liquid Crystals
Yu-Wu Zhong, Yutaka Matsuo, and Eiichi Nakamura
J. Am. Chem. Soc. 2007, 129, 3052-3053.
[LINK]
(50) AlCl3-Mediated Mono-, Di- and Tri-Hydroarylation of [60]fullerene
Akihiko Iwashita, Yutaka Matsuo, and Eiichi Nakamura
Angew. Chem. Int. Ed. 2007, 46, 3513-3516.
[LINK]
(51) Synthesis and Catalytic Activity of η1-Allyl and η3-Allyl, Ethyl, and Hydride Complexes of the Ruthenium-penta(methyl)[60]fullerene
Yutaka Matsuo, Takashi Uematsu, and Eiichi Nakamura
Eur. J. Inorg. Chem. 2007, 2729-2733.
[LINK]
(52) Hoop-shaped Condensed Aromatic System: Synthesis and Structure of Iron- and Ruthenium-Hepta(organo)[60]fullerene Complexes
Yutaka Matsuo, Takeshi Fujita, and Eiichi Nakamura
Chem. Asian J. 2007, 2, 948-955.
[LINK]
(53) New Fluorinated Channel-type Host Compounds
Katharina Reichenbächer, Antonia Neels, Helen Stoeckli-Evans, Poonkodi Balasubramaniyan, Klaus Müller, Yutaka Matsuo, Eiichi Nakamura, Edwin Weber, Jürg Hulliger
Cryst. Growth Des. 2007, 7, 1399-1405.
[LINK]
(54) Synthesis of C5-symmetric Functionalized [60]Fullerenes by Copper-mediated Five-fold Addition of Reformatsky Reagents
Takahiro Nakae, Yutaka Matsuo, and Eiichi Nakamura
Org. Lett. 2008, 10, 621-623.
[LINK]
(55) Addition of Tetrahydrofuran to [60]Fullerene through C-H Bond Activation Induced by Arylzinc Reagents
Yutaka Matsuo, Ying Zhang, and Eiichi Nakamura
Org. Lett. 2008, 10, 1251-1254.
[LINK]
(56) Ruthenium Connection in Fullerene-Ferrocene Arrays. Synthesis of Ru(C60Me5)R(CO)2 (R = C6H4Fc and CCFc) and Their Charge Transfer Properties
Yutaka Matsuo, Keiko Matsuo, Takeshi Nanao, Renata Marczak, S. Shankara Gayathri, Dirk M. Guldi, and Eiichi Nakamura
Chem. Asian J. 2008, 3, 841-848.
[LINK]
(57) Photocurrent-Generating Properties of Organometallic Fullerene Molecules on an Electrode
Yutaka Matsuo, Katsuhiko Kanaizuka, Keiko Matsuo, Yu-Wu Zhong, Takahiro Nakae, and Eiichi Nakamura
J. Am. Chem. Soc. 2008, 130, 5016-5017.
[LINK]
(58) Synthesis of Metal Fullerene Complexes by the Use of Fullerene Halides
Yutaka Matsuo, Yoichiro Kuninobu, Ayako Muramatsu, Masaya Sawamura, and Eiichi Nakamura
Organometallics 2008, 27, 3403-3409.
[LINK]
(59) Group 6 Metal Complexes of the η5-Pentamethyl[60]fullerene
Yutaka Matsuo, Akihiko Iwashita, and Eiichi Nakamura
Organometallics 2008, 27, 4611-4617.
[LINK]
(60) Penta(pyrenyl)[60]fullerenes. Pyrene-Pyrene and [60]Fullerene-Pyrene Interactions in Crystal and in Solution
Yutaka Matsuo, Kouhei Morita, and Eiichi Nakamura
Chem. Asian J. 2008, 8, 1350-1357. (Noyori special issue)
[LINK]
(61) Light Emission of [10]Cyclophenacene through Energy Transfer from Neighboring Carbazolylphenyl Dendrons
Xiaoyong Zhang, Yutaka Matsuo, and Eiichi Nakamura
Org. Lett. 2008, 10, 4145-4147.
[LINK]
(62) Regioselective Synthesis of 1,4-Di(organo)[60]fullerenes through DMF-assisted Mono-addition of Silylmethyl Grignard Reagents and Subsequent Alkylation Reaction
Yutaka Matsuo, Akihiko Iwashita, Yoko Abe, Chang-Zhi Li, Keiko Matsuo, Masahiko Hashiguchi, and Eiichi Nakamura
J. Am. Chem. Soc. 2008, 130, 15429-15436.
[LINK]
(63) Uniquely Shaped Double-Decker Buckyferrocenes - Distinct Electron Donor-Acceptor Interactions
Renata Marczak, Mateusz Wielopolski, S. Shankara Gayathri, Dirk M. Guldi, Yutaka Matsuo, Keiko Matsuo, Kazukuni Tahara, Eiichi Nakamura
J. Am. Chem. Soc. 2008, 130, 16207-16215.
[LINK]
(64) Iron and Ruthenium Nanoparticles in Carbon Prepared by Thermolysis of Buckymetallocenes
Takahiro Nakae, Yutaka Matsuo, Masatoshi Takagi, Yuta Sato, Kazu Suenaga, Eiichi Nakamura
Chem. Asian J. 2009, 4, 457-465.
[LINK]
(65) Synthesis, Electrochemical and Photophysical Properties, and Electroluminescent Performance of the Octa- and Deca-aryl [60]Fullerene Derivatives
Yutaka Matsuo, Yoshiharu Sato, Masahiko Hashiguchi, Keiko Matsuo, Eiichi Nakamura
Adv. Funct. Mater. 2009, 19, 2224-2229.
[LINK]
(66) Ring-opening Reaction of Tetrahydrofuran on the Penta(organo)[60]fullerenes: Synthesis of Hydroxybutyl, Methacrylate, and Norbornene Derivatives
Yutaka Matsuo, Akihiko Iwashita, Hiromi Oyama, Eiichi Nakamura
Tetrahedron Lett. 2009, 50, 3411-3413. (50th Anniversary of TL)
[LINK]
(67) Random Telegraphic Conductance Fluctuation at Au-Pentacene-Au Nanojunctions
Yuki Kihira, Toshihiro Shimada, Yutaka Matsuo, Eiichi Nakamura, Tetsuya Hasegawa
Nano Lett. 2009, 9, 1442-1446.
[LINK]
(68) Penta(organo)[60]fullerenes as Acceptors for Organic Photovoltaic Cells
Takaaki Niinomi, Yutaka Matsuo, Masahiko Hashiguchi, Yoshiharu Sato, Eiichi Nakamura
J. Mater. Chem. 2009, 19, 5804-5811.
[LINK]
(69) Efficient Bidirectional Photocurrent Generation by Self-assembled Monolayer of Penta(aryl)[60]fullerene Phosphonic Acid
Aiko Sakamoto, Yutaka Matsuo, Keiko Matsuo, Eiichi Nakamura
Chem. Asian J. 2009, 4, 1208-1212.
[LINK]
(70) Di- and Trinuclear [70]Fullerene Complexes: Syntheses and Metal-Metal Electronic Interactions
Yutaka Matsuo, Kazukuni Tahara, Takeshi Fujita, Eiichi Nakamura
Angew. Chem. Int. Ed. 2009, 48, 6239-6241.
[LINK]
(71) π-Conjugated Multi-Donor/Acceptor Arrays of Fullerene-Cobaltadithiolene-Tetrathiafulvalene: From Synthesis and Structure to Electronic Interactions
Yutaka Matsuo, Masashi Maruyama, S. Shankara Gayathri, Tomoya Uchida, Dirk M. Guldi, Hideo Kishida, Arao Nakamura, Eiichi Nakamura
J. Am. Chem. Soc. 2009, 131, 12643-12649.
[LINK]
(72) Synthesis of Imino[60]fullerenes Using Nitriles and Trimethylsilylmethyl Triflate
Keiko Matsuo, Yutaka Matsuo, Akihiko Iwashita, Eiichi Nakamura
Org. Lett. 2009, 11, 4192-4194.
[LINK]
(73) Columnar Structure in Bulk Heterojunction in Solution-processable Three-layered p-i-n Organic Photovoltaic Devices Using Tetrabenzoporphyrin Precursor and Silylmethyl[60]fullerene
Yutaka Matsuo, Yoshiharu Sato, Takaaki Niinomi, Iwao Soga, Hideyuki Tanaka, Eiichi Nakamura
J. Am. Chem. Soc. 2009, 131, 16048-16050.
[LINK]
(74) Luminescent Bow-tie-shaped Decaaryl[60]fullerene Mesogens
Chang-Zhi Li, Yutaka Matsuo, Eiichi Nakamura
J. Am. Chem. Soc. 2009, 131, 17058-17059.
[LINK]
(75) Substituent-Dependent Ordering of Adlayer Structures of Fullerene Derivatives: A Scanning Tunneling Microscopy Study
Ting Chen, Ge-Bo Pan, Hui-Juan Yan, Li-Jun Wan, Yutaka Matsuo, Eiichi Nakamura
J. Phys. Chem. C 2010, 114, 3170-3174.
[LINK]
(76) Highly Soluble Penta[(alkyl)dimethylsilylmethyl][60]fullerenes and Their Ruthenium and Palladium Complexes
Yutaka Matsuo, Ayako Muramatsu, Jiang Lu, Eiichi Nakamura
Chem. Lett. 2010, 39, 342-343.
[LINK]
(77) Reductive Benzylation of Dimetallo Hexaaryl[70]fullerenes on the Equatorial Region
Takeshi Fujita, Yutaka Matsuo, Eiichi Nakamura
Chem. Asian J. 2010, 5, 835-840.
[LINK]
(78) C60 Derivatives Having Self-Assembly Capability
Yutaka Matsuo
Fullerene, Nanotubes, and Carbon Nanostructures 2010, 18, 338-352.
[LINK]
(79) Synthesis of Ruthenium Pentamethyl[60]fullerene Complexes bearing Monodentate Diphosphino-methane, -ferrocene, and -butane Ligands
Yutaka Matsuo, Bo Keun Park, Yuichi Mitani, Yu-Wu Zhong, Masashi Maruyama, Eiichi Nakamura
Bull. Korean Chem. Soc. 2010, 31, 697-699.
(80) Loading Pentapod Deca(organo)[60]fullerenes with Electron Donors: From Photophysics to Photoelectrochemical Bilayers
Yutaka Matsuo, Takahiko Ichiki, Shankara Gayathri Radhakrishnan, Dirk M. Guldi, Eiichi Nakamura
J. Am. Chem. Soc. 2010, 132, 6342-6348.
[LINK]
(81) Copper-catalyzed Formal [4 + 2] Annulation between Alkyne and Fullerene Bromide
Zuo Xiao, Yutaka Matsuo, Eiichi Nakamura
J. Am. Chem. Soc. 2010, 132, 12234-12236.
[LINK]
(82) Voltammetry of Half-Sandwich Manganese Group Complexes of η6-PhC3B7H9 and η5-C60Bn2PhH2, Two Ligands That Are Cyclopentadienyl Mimicks
Michael P. Stewart, Robert Butterick III, Larry G. Sneddon, Yutaka Matsuo, William E. Geiger
Inorg. Chim. Acta. 2010, 364, 251-254.
[LINK]
(83) Conical Pentaaryl[60]Fullerene Thiols: Self-Assembled Monolayers on Gold and Photocurrent Generating Property
Yutaka Matsuo, Sebastian Lacher, Aiko Sakamoto, Keiko Matsuo, Eiichi Nakamura
J. Phys. Chem. C 2010, 114, 17741-17752.
[LINK]
(84) Face-to-face C6F5-[60]Fullerene Interaction for Ordering Fullerene Molecules and Application to Thin-film Organic Photovoltaics
Chang-Zhi Li, Yutaka Matsuo, Takaaki Niinomi, Yoshiharu Sato, Eiichi Nakamura
Chem. Commun. 2010, 46, 8582-8584.
[LINK]
(85) Octupole-like Supramolecular Aggregates of Conical Iron Fullerene Complexes into a Three-Dimensional Liquid Crystalline Lattice
Chang-Zhi Li, Yutaka Matsuo, Eiichi Nakamura
J. Am. Chem. Soc. 2010, 132, 15514-15515.
[LINK]
(86) Simple Formation of C60 and C60-Ferrocene Conjugated Monolayers Anchored onto Silicon Oxide with Five Carboxylic Acids and Their Transistor Applications
Yoshimitsu Itoh, Bumjung Kim, Raluca I. Gearba, Noah J. Tremblay, Ron Pindak, Yutaka Matsuo, Eiichi Nakamura, Colin Nuckolls
Chem. Mater. 2011, 23, 970-975.
[LINK]
(87) Synthesis of 1,4-Diaryl[60]fullerenes by Bis-hydroarylation of C60 and Their Use in Solution-processable, Thin-film Organic Photovoltaic cells
Yutaka Matsuo, Ying Zhang, Iwao Soga, Yoshiharu Sato, Eiichi Nakamura
Tetrahedron Lett. 2011, in press.
[LINK]
(88) Aryl-Perfluoroaryl Substituted Tetracene: Induction of Face-to-Face π-π Stacking and Enhancement of Charge Carrier Properties
Toshihiro Okamoto, Katsumasa Nakahara, Akinori Saeki, Shu Seki, Oh Joon Hak, Akkerman Hylke, Bao Zhenan, Yutaka Matsuo
Chem. Mater. 2011, in press.
Accounts and Reviews
(89) Creation of Cyclic π-Electron Conjugated Systems through the Functionalization of Fullerenes and Synthesis of Their Multinuclear Metal Complexes
Yutaka Matsuo
Bull. Chem. Soc. Jpn. 2008, 81, 320-330. (Award Accounts).
[LINK]
(90) Selective Multi-addition of Organocopper Reagents to Fullerenes
Yutaka Matsuo and Eiichi Nakamura
Chem. Rev. 2008, 108, 3016-3028.
[LINK]
Books Chapters
(91) Polymerization of Methyl Methacrylate Initiated by Half-Metallocene Complexes of Tantalum: Ligand Architecture Leading to Living Polymerization in "Future Technology for Polyolefin and Olefin Polymerization Catalysis" Edited by M. Terano and T. Shiono,
Technology and Education Publishers, Tokyo, 2002, pp98-103.
Kazushi Mashima, Yutaka Matsuo, and Kazuhide Tani
(92) Unique Complexation and Catalytic Performance of Zirconium and Hafnium Complexes Bearing N-Aryliminomethylpyrrolyl Ligand in "Current Achievements on Heterogeneous Olefin Polymerization Catalysts" Edited by M. Terano,
Sankeisya Co. Ltd., Nagoya, 2004, pp151-157.
Yutaka Matsuo, Hayato Tsurugi, Takahiro Yasumoto, and Kazushi Mashima
(93) Cyclophenacene Cut Out of Fullerene in "Functional Organic Materials: Syntheses, Strategies and Applications" Edited by Thomas J. J. Müller and Uwe H. F. Bunz
Wiley-VCH, Weinheim, 2007, pp59-80 (Chapter 2).
Yutaka Matsuo and Eiichi Nakamura
[LINK]
(94) Application of Fullerenes to Nanodevices in "Chemistry of Nanocarbons" Edited by F. Wudl, S. Nagase and T. Akasaka
Wiley-Blackwell, 2010, pp173-187 (Chapter 6).
Yutaka Matsuo and Eiichi Nakamura
[LINK]
書籍のチャプター
(1) 有機金属反応剤ハンドブック(玉尾晧平編),化学同人
「リチウム」
中村栄一,松尾 豊
(2) エレクトロニクス用カーボン技術大全集,技術情報協会
「フラーレンの表面修飾」
松尾 豊,中村栄一
(3) ナノカーボンハンドブック(遠藤守信、飯島澄男監修),エヌ・ティー・エス
「羽根付きフラーレンの合成と機能およびフラーレン/フェロセンハイブリッドの合成と電子・光電子機能」
松尾 豊,中村栄一
(4) 超分子サイエンス&テクノロジー(國武豊喜監修、有賀克彦編集),エヌ・ティー・エス
「フラーレンハイブリッド」
松尾 豊
(5) 金属と分子集合ー最新技術と応用ー(松尾 豊監修),シーエムシー出版
「総論」,「フラーレン誘導体の分子集合と有機薄膜太陽電池」
松尾 豊
日本語の総説
(6) 日本結晶学会誌 2006年,vol.48, pp277-282.
「環状π電子共役系・シクロフェナセンの合成と構造研究」
松尾 豊,中村栄一
(7) 有機合成化学協会誌 2007年,vol.65, pp44-53.
「官能基化フラーレンの合成と構造」
松尾 豊,中村栄一
(8) 錯体化学会誌 2010年,vol.55, pp39-51 (Award Accounts).
「フラーレン金属錯体の合成と機能の研究」
松尾 豊
解説記事
(9) 未来材料 2003年,4月号,pp6-12.
「有機フラーレンの形作る超分子構造 -膜と液晶-」
中村栄一,松尾 豊,磯部寛之,澤村正也
(10) Organometallic News 2003, 121, 151.
「新しい種類のカーボンリッチ有機金属化合物」
松尾 豊
(11) ファルマシア,2004年,vol. 40, No. 11,pp1007-1011.
「機能性有機フラーレンを用いた生命科学および材料科学への展開」
中村栄一,松尾 豊,磯部寛之
(12) New Diamond 第80号 2006年,vol.22, p21.
「化学修飾フラーレンに秘められた無限の可能性」
松尾 豊
(13) 化学 2006年,vol. 61, No. 12,pp58-59.
「光電変換デバイス中における分子集合体構造の影響」
松尾 豊
(14) 錯体化学会誌 2007年,vol. 50,pp86-87.
「Gordon Research Conference 2007 (Organometallic Chemistry) 報告」
松尾 豊
(15) Organometallic News 2008年, No. 1, p38.
「異種二核金属錯体ポリマーを用いた合金ナノ粒子の合成」
松尾 豊
(16) 化学 2008年,vol. 63, No. 11,pp30-35.
「フラーレン遷移金属錯体の光電子機能」
松尾 豊
(17) ファルマシア 2009年,vol. 45, No. 3,pp222-226.
「有機フラーレンの合成と機能」
松尾 豊、中村栄一
(18) 東京大学 環境報告書 2009年,p37.
「新しいエネルギー源としての有機薄膜太陽電池」
松尾 豊
(19) 環境安全(東京大学環境安全研究センター) 2010年,3月号,No. 124,pp3-6.
「有機物からなる次世代太陽電池への挑戦」
松尾 豊
(20) 機能材料 2010年,vol. 30, No. 2,pp52-60.
「有機薄膜太陽電池に用いる新規フラーレン誘導体SIMEFの開発」
松尾 豊
(21) OHM(オーム) 2010年,vol. 97,pp2-3.
「低分子の塗布で作る有機薄膜太陽電池」
松尾 豊,佐藤佳晴,中村栄一
(22) Organometallic News 2010年,pp30-35.
「有機薄膜太陽電池の研究開発における化学的アプローチ」
松尾 豊
(23) New Diamond 第99号 2010年,vol.26, pp28-32.
「新規フラーレン誘導体の設計を鍵とする有機薄膜太陽電池の研究開発ー歴史と最新の研究事例ー」
松尾 豊
(24) 未来材料 2011年,1月号,vol.11, pp55-57.
「有機薄膜太陽電池向けフラーレン誘導体の開発」
松尾 豊
(25) 化学と教育 2011年,印刷中.
「フラーレンと有機薄膜太陽電池」
松尾 豊
特許
(1) フラーレン誘導体の製造方法
特開2003-212880
(2) フラーレン誘導体及び金属錯体
特開2003-212881
(3) フラーレン誘導体及びその製造方法
特開2005-015470
(4) フラーレン誘導体及びフラーレン金属錯体、並びにそれらの製造方法
特開2005-232165
(5) フラーレン誘導体及びフラーレン金属錯体、並びにそれらの製造方法
特開2006-206522
(6) 炭素-炭素結合生成反応用触媒
特開2006-247521
(7) 金属含有フラーレン誘導体,それを有する組成物,それを組織化した構造体,並びに,それを用いた液晶ディスプレイ材料,量子デバイス材料及び分子スイッチ材料
特開2007-126389
(8) フラーレン誘導体およびその製造方法
特開2007-217350
(9) 光電変換素子およびその素子を用いた太陽電池
特開2007-217350
(10) フラーレン誘導体の製造方法
特開2008-201721
(11) オレフィン用重合触媒
特開2008-201962
(12) フラーレン誘導体およびその製造方法
特開2008-222583
(13) フラーレン誘導体及びその製造方法
特開2008-231114
(14) 単分子トランジスタおよび単電子トランジスタに用いるフラーレン誘導体
特開2008-288421
(15) 光電変換素子およびその素子を用いた太陽電池
特願2009-013354
(16) フラーレン誘導体の製造方法
特願2009-051894
(17) フラーレン誘導体および当該誘導体を含む光電変換材料
特願2009-121429
(18) フラーレン誘導体,半導体材料,光電変換素子及び太陽電池
特願2009-254456
(19) フラーレン二量体およびその製造方法
特願2010-049276
(20) 電荷輸送材料,それを用いた薄膜及び有機電子デバイス,並びにパイ電子系化合物
特願2010-054572
(21) 光電変換素子,フラーレン化合物の製造方法,及びフラーレン化合物
特願2010-220413
特許(国際)
(1) Preparation of fullerene derivatives and their metal complexes
USA: US 2003139617
(2) Fullerene derivatives and processes for producing the same
USA: US 2005008558
(3) Process for the preparation of fullerene derivative
PCT: WO 2007111226 USA: US 20090118527-A1 Europe: EP 2006276 China: CN 101405252
(4) Fullerene derivatives and ruthenium complexes as liquid crystals
PCT: WO 2007102255 USA: US 20090247777-A1
(5) Photoelectric material containing fullerene derivative
PCT: WO 2007129767 USA: US 20090194158-A1
(6) Photoelectric conversion materials containing fullerene derivatives
PCT: 2007129768 US: 12/299,894
(7) Process for preparing fullerene derivatives
PCT: WO 2008059771 US: 12/514,782 Europe: EP2116521 China: CN 101535220A
Invited Lectures and Seminars (International)
10/2006 Post-conference of 1st International Conference of Cutting-Edge Organic Chemistry in Asia, Hsinchu, Taiwan
05/2007 Shanghai Institute of Organic Chemistry, Shanghai , China
07/2007 Gordon Research Conference, Newport, Rhode Island, USA
07/2007 Merck & Co., Inc., Rahway, New Jersey, USA
07/2007 Pedersen Seminar Series, DuPont, Wilmington, Delaware, USA
03/2008 University of Science and Technology of China, Hefei, China
03/2008 Nankai University, Tianjin, China
03/2008 Tsinghua University, Beijing, China
03/2008 Peking University, Beijing, China
03/2008 Institute of Chemistry, Chinese Academy of Science, Beijing, China
04/2008 43rd EUChem Stereochemistry Conference (Bürgenstock Conference), Switzerland
04/2008 Bern University, Bern, Switzerland
04/2008 Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany
07/2008 NIMS Conference, Tsukuba, Japan
07/2008 Technion, Haifa, Israel
07/2008 Weizmann Institute of Science, Rehovot, Israel
09/2008 GCOE "Chemistry Innovation" Symposium, The University of Tokyo, Tokyo, Japan
07/2009 9th Biennial International Workshop Fullerenes and Atomic Clusters (IWFAC2009), St. Petersburg, Russia
07/2009 International Symposium of Post-silicon Materials and Devices Research Alliance Project, Osaka, Japan
02/2010 University of California, Los Angels, California, USA
02/2010 University of California, Santa Barbara, California, USA
02/2010 Stanford University, California, USA
03/2010 University of Florida, Florida, USA
03/2010 University of North Carolina, Chapel Hill, North Carolina, USA
05/2010 National Taiwan University, Taiwan
06/2010 Chinese Chemical Society, Xiamen, China
09/2010 Advanced Nanomaterials 2010 (Keynote Lecture), Agadir, Morocco
10/2010 UdS-Japanese JSPS Symposium on Supramolecular Nanomaterials Science (Symposium Organizer), Strasbourg, France
11/2010 Japanese-German Frontier of Science (JGFOS) Symposium, Potsdam, Germany

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