GHz-サブTHz電磁波が誘起する分子内電荷の運動を利用した電気特性評価技術の開発
受賞
論文

・ "Carbon Nanotube Wiring of Donor-Acceptor Nanograins by Self-Assembly and Efficient Charge Transport"
T. Umeyama, N. Tezuka, F. Kawashima, S. Seki, Y. Matano, Y. Nakao, T. Shishido, M. Nishi, K. Hirao, H. Lehtivuori, N. V. Tkachenko, H. Lemmetyinen, H. Imahori, Angew. Chem. Int. Ed., (DOI: 10.1002/anie.201007065).

・ "Millimeter-sized Flat Crystalline Sheet Architectures of Fullerene Assemblies with Anisotropic Photoconductivity"
T. Okubo, N. Tanaka, K. H. Kim, H. Anma, S. Seki, A. Saeki, M. Maekawa, T. Kuroda-Sowa, Phys. Chem. Chem. Phys., 13, 4830-4834 (2011).

・ "Millimeter-sized Flat Crystalline Sheet Architectures of Fullerene Assemblies with Anisotropic Photoconductivity"
S. S. Babu, A. Saeki, S. Seki, H. Möhwald, T. Nakanishi, Dalton Trans., 40, 2218-2224 (2011).

・ "Aryl-Perfluoroaryl Substituted Tetracene: Induction of Face-to-Face pi-pi Stacking and Enhancement of Charge Carrier Properties"
T. Okamoto, K. Nakahara, A. Saeki, S. Seki, J. H. Oh, H. Akkerman, Z. Bao, Y. Matsuo, Chem. Mater., 23, 1646-1649 (2011).

・ "Semi-metallic Single-component Crystal of Soluble La@C82 Derivative with High Electron Mobility"
S. Sato, S. Seki, Y. Honsho, L. Wang, H. Nikawa, G. Luo, J. Lu, M. Haranaka, T. Tsuchiya, S. Nagase, T. Akasaka, J. Am. Chem. Soc., 133, 2766-2771 (2011).

・ "Rational Construction of Perylene Bisimide Columnar Superstructures with Biased Helical Sense"
T. Seki, A. Asano, S. Seki, Y. Kikkawa, H. Murayama, T. Karatsu, A. Kitamura, S. Yagai, Chem. Eur. J., 17, 3598-3608 (2011).

・ "Air-Stable n-Type Organic Field-Effect Transistors Based on Solution-Processable Electronegative Oligomers Containing Dicyanomethylene-Substituted Cyclopenta[b]thiophene"
Y. Ie, K. Nishida, H. Tada, A. Asano, A. Saeki, S. Seki, Y. Aso, Chem. Eur. J., 17, 4750-4758 (2011).

・ "Dopant homogeneity and transport properties of impurity-doped oxide nanowires"
A. Klamchuen, T. Yanagida, M. Kanai, K. Nagashima, K. Oka, S. Seki, M. Suzuki, Y. Hidaka, S. Kai, T. Kawai, Appl. Phys. Lett., 98(5), 053107-1-053107-3 (2011).

・ "Synthesis of Metallophthalocyanine Covalent Organic Frameworks that Exhibit High Carrier Mobility and Photoconductivity"
X. Ding, J. Guo, X. Feng, Y. Honsho, J. Guo, S. Seki, P. Maitarad, A. Saeki, S. Nagase, D. Jiang, Angew. Chem. Int. Ed., 50(6), 1289-1293 (2011).

・ "Electron Mobility in a Mercury-mediated Duplex of Triazole-linked DNA (TLDNA)"
H. Isobe, N. Yamazaki, A. Asano, T. Fujino, W. Nakanishi, S. Seki, Chem. Lett., 40(3), 318-319 (2011).

・ "Hierarchical polymer assemblies constructed by the mutual template effect of cationic polymer complex and anionic supramolecular nanofiber"
K. Sugikawa M. Numata, D. Kinoshita, K. Kaneko, K. Sada, A. Asano, S. Seki, S. Shinkai, Org. Biomol. Chem., 9(1), 146-153 (2011).

・ "Supramolecularly Engineered Aggregation of a Dipolar Dye: Vesicular and Ribbonlike Architectures"
S. Yagai, Y. Nakano, S. Seki, A. Asano, T. Okubo, T. Isoshima, T. Karatsu, A. Kitamura, Y. Kikkawa, Angew. Chem. Int. Ed., 49(51), 9990-9994 (2010).

・ "Good Solvent Effects of C70 Cluster Formations and Their Electron-Transporting and Photoelectrochemical Properties"

・ "N. Tezuka, T. Umeyama, Y. Matano, T. Shishido, M. Kawasaki, M. Nishi, K. Hirao, L. Lehtivuori, N. V. Tkachenko, H. Lemmetyinen, Y. Honsho, S. Seki, H. Imahori, J. Phys. Chem. B, 114(45), 14287-14297 (2010)."

・ "Programmed High-Hole-Mobility Supramolecular Polymers from Disk-Shaped Molecules"
W. Zhang, K. Ochi, M. Fujiki, M. Naito, M. Ishikawa, K. i-. Kaneto, W. Takashima, A. Saeki, S. Seki, Adv. Funct. Mater., 20(22), 3941-3947 (2010).

・ "Structural and Electronic Properties of Extremely Long Electron-Conductive Perylene Bisimide Nanofibers Formed through a Stoichiometrically-Mismatched Complexation between Complimentary Multiple Hydrogen-Bonding Modules"
S. Yagai, T. Seki, H. Murayama, Y. Wakikawa, T. Ikoma, Y. Kikkawa, T. Karatsu, A. Kitamura, Y. Honsho, S. Seki, Small, 6(23), 2731-2740 (2010).

・ "A Self-Threading Polythiophene: Defect-Free Insulated Molecular Wires Endowed with Long Effective Conjugation Length"
K. Sugiyasu, Y. Honsho, R. M. Harrison, A. Sato, T. Yasuda, S. Seki, M. Takeuchi, J. Am. Chem. Soc., 132(42), 14754-14756 (2010).

・ "Supramolecular Structures and Photoelectronic Properties of the Inclusion Complex of a Cyclic Free-Base Porphyrin Dimer and C60"
H. Nobukuni, Y. Shimazaki, H. Uno, Y. Naruta, K. Ohkubo, T. Kojima, S. Fukuzumi, S. Seki, H. Sakai, T. Hasobe, F. Tani, Chem. Eur. J., 16(38), 11611-11623 (2010).

・ "Electronic and Optical Properties in the Solid-State Molecular Assemblies of Anion-Responsive Pyrrole-Based π-Conjugated Systems"
H. Maeda, Y. Bando, Y. Haketa, Y. Honsho, S. Seki, H. Nakajima, N. Tohnai, Chem. Eur. J., 16(36), 10994-11002 (2010).

・ "Solution Phase Epitaxial Self-Assembly and High Charge-Carrier Mobility Nanofibers of Semiconducting Molecular Gelators"
S. Prasanthkumar, A. Saeki, S. Seki and A. Ajayaghosh, J. Am. Chem. Soc., 132(26), 8866-8867 (2010).

・ "Use of Side-Chain Incompatibility for Tailoring Long-Range p/n Heterojunctions: Photoconductive Nanofibers Formed by Self-Assembly of an Amphiphilic Donor-Acceptor Dyad Consisting of Oligothiophene and Perylenediimide"
W.-S. Li, A. Saeki, Y. Yamamoto, T. Fukushima, S. Seki, N. Ishii, K. Kato, M. Takata, T. Aida, Chem. Asian J., 5(7), 1566-1572 (2010).

・ "Evidence of electron conductivity in polysilanes and its implications in design of ultraviolet emitting devices"
Deepak, N. Banerjee, S. Seki, J. Appl. Phys., 107(12), 124513 (2010).

・ "Flowerlike supramolecular architectures assembled from C-60 equipped with a pyridine substituent"
X. A. Zhang, T. Nakanishi, T. Ogawa, A. Saeki, S. Seki, Y. F. Shen, Y. Yamauchi, M. Takeuchi, Chem. Commun., 46, 8752-8754 (2010).

・ "Micrometer-Sized Magnetic Patterning of FeRh Films Using an Energetic Ion Microbeam"
N. Fujita, T. Matsui, S. Kosugi, T. Satoh, Y. Saitoh, K. Takano, M. Koka, T. Kamiya, S. Seki, A. Iwase, Jpn. J. Appl. Phys., 49(6-1), 060211 (2010).

・ "Photoinduced vitrification near the surfaces of single crystals of azobenzene-based molecular materials with glass-forming ability"
H. Nakano, S. Seki, H. Kageyama, Phys. Chem. Chem. Phys., 12(28), 7772-7774 (2010).

・ "Light-Harvesting Conjugated Microporous Polymers: Rapid and Highly Efficient Flow of Light Energy with a Porous Polyphenylene Framework as Antenna"
L Chen, Y Honsho, S Seki, D. Jiang, J. Am. Chem. Soc., 132(19), 6742-6748 (2010).

・ "Chiroselective Assembly of a Chiral Porphyrin-Fullerene Dyad: Photoconductive Nanofiber with a Top-Class Ambipolar Charge-Carrier Mobility"
Y. Hizume, K. Tashiro, R. Charvet, Y. Yamamoto, A. Saeki, S. Seki, T. Aida, J. Am. Chem. Soc., 132(19), 6628-6629 (2010).

・ "Selective Formation and Efficient Photocurrent Generation of [70]Fullerene?Single-Walled Carbon Nanotube Composites"
T. Umeyama, N. Tezuka, S. Seki, Y. Matano, M. Nishi, K. Hirao, H. Lehtivuori, N. V. Tkachenko, H. Lemmetyinen, Y. Nakao, S. Sakaki, H. Imahori, Adv. Mater., 22(15), 1767-1770 (2010).

・ "Photogeneration of charge carrier correlated with amplified spontaneous emission in single crystals of a thiophene/phenylene co-oligomer"
A. Saeki, S. Seki, Y. Shimizu, T. Yamao, S. Hotta, J. Chem. Phys., 132(13), 134509/1-134509/7 (2010).

" ・ "Discotic columnar mesophases derived from 'rod-like' π-conjugated anion-responsive acyclic oligopyrroles"
H. Maeda, Y. Terashima, Y. Haketa, A. Asano, Y. Honsho, S. Seki, M. Shimizu, H. Mukai, K. Ohta, Chem. Commun., 46, 4559-4561 (2010).

・ "Effects of the silicon core structures on the hole mobility of star-shaped oligothiophenes"
J. Ohshita, Y. Hatanaka, S. Matsui, T. Mizumo, Y. Kunugi, Y. Honsho, A. Saeki, S. Seki, J. Tibbelin, H. Ottosson, T. Takeuchi, Dalton Trans., 39, 9314-9320 (2010).

・ "Comparison of Cluster Formation, Film Structure, Microwave Conductivity, and Photoelectrochemical Properties of Composites Consisting of Single-Walled Carbon Nanotubes with C60, C70, and C84"
N. Tezuka, T. Umeyama, S. Seki, Y. Matano, M. Nishi, K. Hirao, H. Imahori, J. Phys. Chem. C, 114(7), 3235-3247 (2010).

・ "Hexabenzocoronene Graphitic Nanotube Appended with Dithienylethene Pendants: Photochromism for the Modulation of Photoconductivity"
Y. He, Y. Yamamoto, W. Jin, T. Fukushima, A. Saeki, S. Seki, N. Ishii, T. Aida, Adv. Mater., 22(7), 829-832 (2010).

・ "Interfacial effect on metal/oxide nanowire junctions"
K. Nagashima, T. Yanagida, A. Klamchuen, M. Kanai, K. Oka, S. Seki, T. Kawai, Appl. Phys. Lett., 96(7), 073110 (2010).

・ "Physical Properties, Charge Carrier Mobility, and Photovoltaic Performance of Dendritic Oligothiophene Bearing Naphthalene Bis(dicarboximide) Groups"
Y. Ie, T. Uto, Y. Honsho, S. Seki, M. Karakawa, Y. Aso, Jpn. J. Appl. Phys., 49(1), 01AC03 (2010).

・ "QCM Gas Sensor with Organic Nanowire Film as Molecular Recognition Membrane"
Y. Dehari, Y. Takei, S. Koyama, H. Nanto, S. Seki, Sensors and Materials, 22(4), 175-181 (2010).

・ "Insulated Molecular Wire with Highly Conductive pi-Conjugated Polymer Core"
J. Terao, Y. Tanaka, S. Tsuda, N. Kambe, M. Taniguchi, T. Kawai, A. Saeki, S. Seki, J. Am. Chem. Soc., 131(50), 18046-18047 (2009).

・ "Block-Copolymer-Nanowires with Nanosized Domain Segregation and High Charge Mobilities as Stacked p/n Heterojunction Arrays for Repeatable Photocurrent Switching"
R. Charvet, S. Acharya, J. P. Hill, M. Akada, M. Liao, S. Seki, Y. Honsho, A. Saeki, K. Ariga, J. Am. Chem. Soc., 131(50), 18030-18031 (2009).

・ "Ambipolar-Transporting Coaxial Nanotubes with a Tailored Molecular Graphene-Fullerene Heterojunction"
Y. Yamamoto, G. Zhang, W. Jin, T. Fukushima, T. Minari, N. Ishii, A. Saeki, S. Seki, S. Tagawa, T. Minari, K. Tsukagoshi, T. Aida, Proc. Nat. Acad. Sci., 106(50), 21051-21056 (2009).

・ "Anisotropic High Electron Mobility and Photodynamics of a Self-Assembled Porphyrin Nanotube Including C60 Molecules"
H. Nobukuni, F. Tani, Y. Shimazaki, Y. Naruta, K. Ohkubo, T. Nakanishi, T. Kojima, S. Fukuzumi, S. Seki, J. Phys. Chem. C, 113(45), 19694-19699 (2009).

・ "Charge Transport Properties of Hexabenzocoronene Nanotubes by Field Effect: Influence of the Oligoether Side Chains on the Mobility"
Y. Yamamoto,W. Jin, T. Fukushima, T. Minari, K. Tsukagoshi, A. Saeki, S. Seki, S. Tagawa, T. Aida, Chem. Lett., 38(9), 888-889 (2009).

・ "Comprehensive Evaluation of Electron Mobility for Trifluoroacetyl-Terminated Electronegative Conjugated Oligomer"
Y. Ie, M. Nitani, T. Uemura, Y. Tominari, J. Takeya, Y. Honsho, A. Saeki, S. Seki, Y. Aso, J. Phys. Chem. C, 116(39), 17189-17193 (2009).

・ "Bicontinuous Cubic' Liquid Crystalline Materials from Discotic Molecules: A Special Effect of Paraffinic Side Chains with Ionic Liquid Pendants"
Md. A. Alam, J. Motoyanagi, Y. Yamamoto, T. Fukushima, J. Kim, K. Kato, M. Takata, A. Saeki, S. Seki, S. Tagawa, T. Aida, J. Am. Chem. Soc., 131(49), 17722-17723 (2009).

・ "Interconvertible Oligothiophene Nanorods and Nanotapes with High Charge Carrier Mobilities"
S. Yagai, T. Kinoshita, Y. Kikkawa, T. Karatsu, A. Kitamura, Y. Honsho, S. Seki, Chem. Eur. J., 15(37), 9320-9324 (2009).

・ "Impact of Side-Chain Length on Alternating Current Mobility of Charge Carrier in Regioregular Poly(3-alkylthiophene) Films"
A. Saeki, S. I. Ohsaki, Y. Koizumi, S. Seki, Synthetic Metal, 159(17-18), 1800-1803 (2009).

・ "Importance of Doping Dynamics on Transport Properties of Sb-doped SnO2 Nanowires"
A. Klamchuen, T. Yanagida, K. Nagashima, S. Seki, K. Oka, M. Taniguchi, T. Kawai, Appl. Phys. Lett., 95(5), 053105-1-053105-3 (2009).

・ "Organic Conducting Wire Formation on a TiO2 Nanocrystalline Structure: Towards Long-Lived Charge Separated Systems"
Y. Tachibana, S. Makuta, Y. Otsuka, J. Terao, S. Tsuda, N. Kambe, S. Seki, S. Kuwabata, Chem. Comm., 2009 (29), 4360-4362 (2009).

・ "Sugar Nanowires Based on Cyclodextrin Prepared by Single Particle Nano-fabrication Technique"
S. Watanabe, S. Seki, M. Sugimoto, M. Yoshikawa, S. Tagawa, S. Tsukuda, Shun-Ichiro Tanaka, Radiat. Phys. Chem., 78(12), 1071-1075 (2009).

・ "Conformational Relaxation of σ-Conjugated Polymer Radical Anion on Picosecond Scale"
Y. Ohnishi, A. Saeki, S. Seki, S. Tagawa, J. Chem. Phys., 130(20), 204907-1-204907-6 (2009).
(ア) (Selected for the June 1, 2009 issue of Virtual Journal of Biological Physics Research)

・ "Unusual Side Chain Effects on Charge-Carrier Lifetime in Discotic Liquid Crystals"
J. Motoyanagi, Y. Yamamoto, A. Saeki, M. A. Alam, A. Kimoto, A. Kosaka, T. Fukushima, S. Seki, S. Tagawa, T. Aida, Chem. Asian J., 4(6), 876-880 (2009).

・ "Specific surface effect on transport properties of NiO/MgO heterostructured nanowires"
K. Oka, T. Yanagida, K. Nagashima, H. Tanaka, S. Seki, Y. Honsho, M. Ishimaru, A. Hirata, T. Kawai, Appl. Phys. Lett., 95(13), 133110-1-133110-3 (2009).

・ "Noncovalently Netted, Photoconductive Sheets with Extremely High Carrier Mobility and Conduction Anisotropy from Triphenylene-Fused Metal Trigon Conjugates"
L. Chen, J. Kim, T. Ishizuka, Y. Honsho, A. Saeki, S. Seki, H. Ihee, D. Jiang, J. Am. Chem. Soc., 131(21), 7287-7292 (2009).

・ "Photovoltaic performance and charge carrier mobility of dendritic oligothiophene bearing perylene bis(dicarboximide) groups"
Y. Ie, T. Uto, A. Saeki, S. Seki, S. Tagawa, Y. Aso, Synthetic Metal, 159(9-10), 797-801 (2009).

・ "Noncovalent Assembly of Benzene-Bridged Metallosalphen Dimers: Photoconductive Tapes with Large Carrier Mobility and Spatially Distinctive Conduction Anisotropy"
L. Chen, L. Wang, X. Gao, S. Nagase, Y. Honsho, A. Saeki, S. Seki, D. Jiang, Chem. Comm., 2009(21), 3119-3121 (2009).

・ "Intramolecular Mobility of Holes along Rod-like Helical Si-backbones in Optically Active Polysilanes"
Y. Honsho, A. Asano, S. Seki, T. Sunagawa, A. Saeki, Synthetic Metal, 159(9-10), 843-846 (2009).

・ "Anisotropic Electron Transport Properties in Sumanene Crystal"
T. Amaya, S. Seki, T. Moriuchi, K. Nakamoto, T. Nakata, H. Sakane, A. Saeki, S. Tagawa, T. Hirao, J. Am. Chem. Soc., 131(2), 408-409 (2009).
(ア) (Highlighted in the April 1, 2009 issue of Nature Asia Materials)

特許
その他

・ 関 修平, 福松嵩博, 佐伯昭紀, 高分子論文集 68 (2011) 53

・ 関 修平, 佐伯昭紀 有機合成化学協会誌 69 (2011) 140.

・ 関 修平 「共役分子軸の本質的電荷輸送特性評価」第59回高分子討論会 招待講演